The Stokes constants for a cluster of transition points

1988 ◽  
Vol 104 (1) ◽  
pp. 153-179 ◽  
Author(s):  
Nanny Fröman ◽  
Per Olof Fröman ◽  
Bengt Lundborg

AbstractThe connection problems associated with the one-dimensional Schrödinger equation in the presence of a general isolated cluster containing an unspecified number of complex transition points in unspecified positions can be studied by means of the phase-integral method developed by Fröman and Fröman. Any anti-Stokes line, i.e. any line in the complex z-plane on which the solutions behave as travelling waves with constant flow, must asymptotically (i.e. in the limit of large values of |z|) point in one of m +2 possible directions, which divide the region around the cluster into m +2 sectors, where m is the degree of the cluster. The tracing of these waves from an anti-Stokes line, bounding a sector, to an anti-Stokes line constituting the other boundary of the same sector is expressed by means of the Stokes constant for the sector in question. This paper examines the relation between these m + 2 Stokes constants in the general case when the transition points in the cluster may also be close-lying in the sense that it is impossible to treat them individually, when the solutions are traced. Under the assumption that the effective potential in the Schrodinger equation is a regular analytic function in a sufficiently large region containing the cluster, it is shown that the m + 2 Stokes constants are in general constrained by three algebraic relations, which are obtained for arbitrary m. The cases m = 1, 2, 3 and 4 are worked out in detail.

2003 ◽  
Vol 14 (08) ◽  
pp. 1087-1105 ◽  
Author(s):  
ZHONGCHENG WANG ◽  
YONGMING DAI

A new twelfth-order four-step formula containing fourth derivatives for the numerical integration of the one-dimensional Schrödinger equation has been developed. It was found that by adding multi-derivative terms, the stability of a linear multi-step method can be improved and the interval of periodicity of this new method is larger than that of the Numerov's method. The numerical test shows that the new method is superior to the previous lower orders in both accuracy and efficiency and it is specially applied to the problem when an increasing accuracy is requested.


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