scholarly journals Innovative Electrolytes Based on Ionic Liquids and Polymers for Next-Generation Solid-State Batteries

2019 ◽  
Vol 52 (3) ◽  
pp. 686-694 ◽  
Author(s):  
Maria Forsyth ◽  
Luca Porcarelli ◽  
Xiaoen Wang ◽  
Nicolas Goujon ◽  
David Mecerreyes
Author(s):  
James Dawson ◽  
Theodosios Famprikis ◽  
Karen E Johnston

Current commercial batteries cannot meet the requirements of next-generation technologies, meaning that the creation of new high-performance batteries at low cost is essential for the electrification of transport and large-scale...


RSC Advances ◽  
2020 ◽  
Vol 10 (38) ◽  
pp. 22304-22310
Author(s):  
Kazuhiro Hikima ◽  
Nguyen Huu Huy Phuc ◽  
Hirofumi Tsukasaki ◽  
Shigeo Mori ◽  
Hiroyuki Muto ◽  
...  

The performances of next generation all-solid-state batteries might be improved by using multi-valent cation doped Li6PS5Cl solid electrolytes.


1983 ◽  
Vol 44 (C3) ◽  
pp. C3-567-C3-572 ◽  
Author(s):  
F. Bénière ◽  
D. Boils ◽  
H. Cánepa ◽  
J. Franco ◽  
A. Le Corre ◽  
...  

2019 ◽  
Vol 92 (11) ◽  
pp. 430-434
Author(s):  
Akitoshi HAYASHI ◽  
Atsushi SAKUDA ◽  
Masahiro TATSUMISAGO

2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.


2019 ◽  
Author(s):  
Florian Strauss ◽  
Lea de Biasi ◽  
A-Young Kim ◽  
Jonas Hertle ◽  
Simon Schweidler ◽  
...  

Measures to improve the cycling performance and stability of bulk-type all-solid-state batteries (SSBs) are currently being developed with the goal of substituting conventional Li-ion battery (LIB) technology. As known from liquid electrolyte based LIBs, layered oxide cathode materials undergo volume changes upon (de)lithiation, causing mechanical degradation due to particle fracture, among others. Unlike solid electrolytes, liquid electrolytes are somewhat capable of accommodating morphological changes. In SSBs, the rigidity of the materials used typically leads to adverse contact loss at the interfaces of cathode material and solid electrolyte during cycling. Hence, designing zero- or low-strain electrode materials for application in next-generation SSBs is desirable. In the present work, we report on novel Co-rich NCMs, NCM361 (60% Co) and NCM271 (70% Co), showing minor volume changes up to 4.5 V vs Li<sup>+</sup>/Li, as determined by <i>operando</i> X-ray diffraction and pressure measurements of LIB pouch and pelletized SSB cells, respectively. Both cathode materials exhibit good cycling performance when incorporated into SSB cells using argyrodite Li<sub>6</sub>PS<sub>5</sub>Cl solid electrolyte, albeit their morphology and secondary particle size have not yet been optimized.


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