New Chiral Hydrogen-Bonded Organic Framework Based on Substituted Diarylacetylene Dicarboxylic Acid

2020 ◽  
Vol 20 (6) ◽  
pp. 3713-3721
Author(s):  
Vladimir V. Veselovsky ◽  
Antonina V. Lozanova ◽  
Vera I. Isaeva ◽  
Vera D. Nissenbaum ◽  
Nikolai A. Davshan ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Organic Framework ◽  
Hydrogen Bonded

scholarly journals Water Photo-Electrooxidation Using Mats of TiO2 Nanorods, Surface Sensitized by a Metal–Organic Framework of Nickel and 1,2-Benzene Dicarboxylic Acid

Hydrogen ◽  
2021 ◽  
Vol 2 (1) ◽  
pp. 58-75
Author(s):  
Sheng-Mu You ◽  
Waleed M. A. El Rouby ◽  
Loïc Assaud ◽  
Ruey-An Doong ◽  
Pierre Millet
Keyword(s):  
Dicarboxylic Acid ◽  
Electrochemical Impedance ◽  
Metal Organic Framework ◽  
Linear Sweep Voltammetry ◽  
Tio2 Nanorods ◽  
Tem Analysis ◽  
Vis Spectroscopy ◽  
Metal Organic ◽  
Benzene Dicarboxylic Acid ◽  
Organic Framework

Photoanodes comprising a transparent glass substrate coated with a thin conductive film of fluorine-doped tin oxide (FTO) and a thin layer of a photoactive phase have been fabricated and tested with regard to the photo-electro-oxidation of water into molecular oxygen. The photoactive layer was made of a mat of TiO2 nanorods (TDNRs) of micrometric thickness. Individual nanorods were successfully photosensitized with nanoparticles of a metal–organic framework (MOF) of nickel and 1,2-benzene dicarboxylic acid (BDCA). Detailed microstructural information was obtained from SEM and TEM analysis. The chemical composition of the active layer was determined by XRD, XPS and FTIR analysis. Optical properties were determined by UV–Vis spectroscopy. The water photooxidation activity was evaluated by linear sweep voltammetry and the robustness was assessed by chrono-amperometry. The OER (oxygen evolution reaction) photo-activity of these photoelectrodes was found to be directly related to the amount of MOF deposited on the TiO2 nanorods, and was therefore maximized by adjusting the MOF content. The microscopic reaction mechanism which controls the photoactivity of these photoelectrodes was analyzed by photo-electrochemical impedance spectroscopy. Microscopic rate parameters are reported. These results contribute to the development and characterization of MOF-sensitized OER photoanodes.

A Novel Hydrogen-Bonded Organic Framework with Highly Permanent Porosity for Boosting Ethane/Ethylene Separation

2021 ◽  
pp. 497-503
Author(s):  
Jia-Xin Wang ◽  
Xiao-Wen Gu ◽  
Yu-Xin Lin ◽  
Bin Li ◽  
Guodong Qian
Keyword(s):  
Organic Framework ◽  
Hydrogen Bonded

A Rod‐Packing Hydrogen‐Bonded Organic Framework with Suitable Pore Confinement for Benchmark Ethane/Ethylene Separation

2021 ◽  
Vol 60 (18) ◽  
pp. 10304-10310 ◽  
Author(s):  
Xu Zhang ◽  
Jia‐Xin Wang ◽  
Libo Li ◽  
Jiyan Pei ◽  
Rajamani Krishna ◽  
...  
Keyword(s):  
Organic Framework ◽  
Hydrogen Bonded

Guest-Regulated Luminescence and Force-Stimuli Response of a Hydrogen-Bonded Organic Framework

2021 ◽  
Author(s):  
Yanning Han ◽  
Tong Zhang ◽  
Xinyu Chen ◽  
Qiao Chen ◽  
Jingjun Hao ◽  
...  
Keyword(s):  
Stimuli Response ◽  
Organic Framework ◽  
Hydrogen Bonded

ChemInform Abstract: A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols.

ChemInform ◽  
2014 ◽  
Vol 45 (30) ◽  
pp. no-no
Author(s):  
Peng Li ◽  
Yabing He ◽  
Jie Guang ◽  
Linghong Weng ◽  
John Cong-Gui Zhao ◽  
...  
Keyword(s):  
Secondary Alcohols ◽  
Enantioselective Separation ◽  
Organic Framework ◽  
Hydrogen Bonded

A fluorescent zirconium organic framework displaying rapid and nanomolar level detection of Hg(II) and nitroantibiotics

2022 ◽  
Author(s):  
Subhrajyoti Ghosh ◽  
Felix Steinke ◽  
Abhijeet Rana ◽  
Shyam Biswas
Keyword(s):  
Acetic Acid ◽  
Dicarboxylic Acid ◽  
Metal Organic Framework ◽  
Solvothermal Reaction ◽  
Metal Organic ◽  
Organic Framework

The solvothermal reaction of ZrCl4 with benzo[1,2-b:4,5-b’]dithiophene-2,6-dicarboxylic acid linker molecule in presence of trifluoro acetic acid modulator afforded the UiO-66 type of metal organic framework (MOF) (IITG-5, IITG = Indian...

scholarly journals Alignment of paired molecules of C60 within a hexagonal platform networked through hydrogen-bonds

2016 ◽  
Vol 52 (63) ◽  
pp. 9781-9784 ◽  
Author(s):  
Ichiro Hisaki ◽  
Shoichi Nakagawa ◽  
Hiroyasu Sato ◽  
Norimitsu Tohnai
Keyword(s):  
Hydrogen Bonds ◽  
Low Density ◽  
Organic Framework ◽  
Hydrogen Bonded

A hydrogen-bonded low-density organic framework achieved periodic alignment of paired molecules of C60.

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