Grafting Free Carboxylic Acid Groups onto the Pore Surface of 3D Porous Coordination Polymers for High Proton Conductivity

2019 ◽  
Vol 31 (20) ◽  
pp. 8494-8503 ◽  
Author(s):  
Yuanmeng Tian ◽  
Gan Liang ◽  
Tao Fan ◽  
Jin Shang ◽  
Shanshan Shang ◽  
...  
2009 ◽  
Vol 8 (10) ◽  
pp. 831-836 ◽  
Author(s):  
Sareeya Bureekaew ◽  
Satoshi Horike ◽  
Masakazu Higuchi ◽  
Motohiro Mizuno ◽  
Takashi Kawamura ◽  
...  

2010 ◽  
pp. 232-237 ◽  
Author(s):  
Sareeya Bureekaew ◽  
Satoshi Horike ◽  
Masakazu Higuchi ◽  
Motohiro Mizuno ◽  
Takashi Kawamura ◽  
...  

2018 ◽  
Vol 47 (43) ◽  
pp. 15288-15292 ◽  
Author(s):  
Jingyu Shi ◽  
Jing Li ◽  
Hongmei Zeng ◽  
Guohong Zou ◽  
Qinghua Zhang ◽  
...  

Presented here are two water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides, which show high proton conductivities on the order of 10−3 S cm−1 at 85 °C under 98% relative humidity.


2015 ◽  
Vol 44 (3) ◽  
pp. 948-954 ◽  
Author(s):  
Shu-Na Zhao ◽  
Xue-Zhi Song ◽  
Min Zhu ◽  
Xing Meng ◽  
Lan-Lan Wu ◽  
...  

Three MOFs with different structures all exhibit proton conduction behavior, especially for the Cu compound with a proton conductivity of 3.46 × 10−3 S cm−1 at 368 K and 95% RH.


2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.


2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.


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