Assembly of three coordination polymers based on a sulfonic–carboxylic ligand showing high proton conductivity

2015 ◽  
Vol 44 (3) ◽  
pp. 948-954 ◽  
Author(s):  
Shu-Na Zhao ◽  
Xue-Zhi Song ◽  
Min Zhu ◽  
Xing Meng ◽  
Lan-Lan Wu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Coordination Polymers ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Conduction Behavior

Three MOFs with different structures all exhibit proton conduction behavior, especially for the Cu compound with a proton conductivity of 3.46 × 10−3 S cm−1 at 368 K and 95% RH.

A water-stable Ni(ii) diphosphonate exhibiting water vapor adsorption and water-assisted high proton conductivity

2019 ◽  
Vol 43 (2) ◽  
pp. 807-812 ◽  
Author(s):  
Hailong Xu ◽  
Lu Feng ◽  
Wentao Huang ◽  
Qiaoyun Wang ◽  
Hong Zhou
Keyword(s):  
Thermal Properties ◽  
Water Vapor ◽  
Proton Conductivity ◽  
Proton Conduction ◽  
Water Vapor Adsorption ◽  
Water Stability ◽  
High Proton Conductivity ◽  
Vapor Adsorption ◽  
High Proton

A new nickel phosphonate has been synthesized, and its thermal properties, water stability, water vapor adsorption and proton conduction have been investigated.

scholarly journals Twist and sliding dynamics between interpenetrated frames in Ti-MOF revealing high proton conductivity

2020 ◽  
Vol 11 (15) ◽  
pp. 3978-3985 ◽  
Author(s):  
Jing Cao ◽  
Wenjie Ma ◽  
Kangjie Lyu ◽  
Lin Zhuang ◽  
Hengjiang Cong ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Sliding Dynamics

Twist and sliding dynamics observed in a titanium catecholate MOF induced by imidazole for efficient proton conduction.

Water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides showing high proton conductivity

2018 ◽  
Vol 47 (43) ◽  
pp. 15288-15292 ◽  
Author(s):  
Jingyu Shi ◽  
Jing Li ◽  
Hongmei Zeng ◽  
Guohong Zou ◽  
Qinghua Zhang ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Proton Conductivity ◽  
Coordination Polymers ◽  
High Proton Conductivity ◽  
Cyclic Dipeptides ◽  
High Proton

Presented here are two water stable oxalate-based coordination polymers with in situ generated cyclic dipeptides, which show high proton conductivities on the order of 10−3 S cm−1 at 85 °C under 98% relative humidity.

Dual-cubic-cage based lanthanide sulfate–carboxylpyrazolate frameworks with high hydrolytic stability and remarkable proton conduction

2019 ◽  
Vol 55 (17) ◽  
pp. 2497-2500 ◽  
Author(s):  
Liang He ◽  
Jayanta Kumar Nath ◽  
Er-Xia Chen ◽  
Heng-Dong Lai ◽  
Shan-Lin Huang ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Proton Conductivity ◽  
Hydrolytic Stability ◽  
Hydrothermal Condition ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton

Lanthanide sulfate–carboxylpyrazolate nets, which have double cuboid cavities, encapsulated single-ion hydrates, tolerance in water for 6 months and even under a 200 °C hydrothermal condition tested for 3 days, and high proton-conductivity of over 10−3 S cm−1 at 25 °C and at 97% relative humidity are reported.

Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

2020 ◽  
Vol 56 (3) ◽  
pp. 391-394 ◽  
Author(s):  
Shan Zhang ◽  
Ying Lu ◽  
Xiu-Wei Sun ◽  
Zhuo Li ◽  
Tian-Yi Dang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transformation ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Crystal Structural ◽  
Inorganic Framework ◽  
Phosphate Groups ◽  
New Framework

A pure-inorganic framework 1 underwent a SCSC transformation to form a new framework 1′, which has high proton conductivity.

scholarly journals One-dimensional imidazole aggregate in aluminium porous coordination polymers with high proton conductivity

2009 ◽  
Vol 8 (10) ◽  
pp. 831-836 ◽  
Author(s):  
Sareeya Bureekaew ◽  
Satoshi Horike ◽  
Masakazu Higuchi ◽  
Motohiro Mizuno ◽  
Takashi Kawamura ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Coordination Polymers ◽  
Porous Coordination Polymers ◽  
High Proton Conductivity ◽  
One Dimensional ◽  
High Proton

A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

2017 ◽  
Vol 5 (28) ◽  
pp. 14525-14529 ◽  
Author(s):  
Hao Wu ◽  
Fan Yang ◽  
Xiu-Liang Lv ◽  
Bin Wang ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Density ◽  
Carboxylic Group ◽  
High Proton Conductivity ◽  
High Proton ◽  
Carboxylic Groups ◽  
Metal Organic ◽  
Organic Framework

A highly stable porphyrinic MOF with free-carboxylic group functionalized pore surfaces exhibits a high proton conductivity of 3.9 × 10−2 S cm−1 at 80 °C and 97% RH, which is comparable to most of the reported proton conductive MOFs.

PbX2(OOCMMIm) (X = Cl, Br): photoluminescent organic–inorganic hybrid lead halide compounds with high proton conductivity

2019 ◽  
Vol 48 (20) ◽  
pp. 6690-6694 ◽  
Author(s):  
Liao-Kuo Gong ◽  
Ke-Zhao Du ◽  
Xiao-Ying Huang
Keyword(s):  
Proton Conductivity ◽  
Proton Conduction ◽  
Photoluminescence Properties ◽  
High Proton Conductivity ◽  
Inorganic Hybrid ◽  
High Proton ◽  
Lead Halide

Differences in electronegativity and hydrophilicity of halogens result in various proton conduction and photoluminescence properties in [PbX2(OOCMMIm)].

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