Effect of Acetic Acid Addition on Decomposition of Xylose in Supercritical Water

2018 ◽  
Vol 32 (2) ◽  
pp. 1754-1760 ◽  
Author(s):  
Tanawan Chalermsaktrakul ◽  
Yukihiko Matsumura
2004 ◽  
Vol 2 (1) ◽  
pp. 220-233 ◽  
Author(s):  
Jiří Verner ◽  
Milan Potáček

AbstractAromatic 1,4-diazabuta-1,3-dienes in glacial acetic acid with thiocyanates produce via criss-cross cycloaddition reactions the corresponding perhydroimidazo[4,5-d]imidazole-2,5-dithiones. When a mixture of thiocyanate and cyanate in a proper ratio was reacted together, nonsymmetrical 5-thioxo-perhydroimidazo[4,5-d]imidazole-2-ones were isolated. With cyanates substituted aromatic 1,4-diazabuta-1,3-dienes afforded product of acetic acid addition to primary formed 1,3-dipole intermediate 5-(4-substituted phenylamino)-3-(4-substituted phenyl)-2-oxoimidazolidin-4-yl acetate.


1991 ◽  
Vol 23 (1-3) ◽  
pp. 389-398 ◽  
Author(s):  
Abdullah Shanableh ◽  
Earnest F. Gloyna

Environmental contaminants can be eliminated through the use of SCWO techniques. A comprehensive supercritical oxidation (SCWO) research laboratory, including bench and pilot-scale facilities has been developed. High temperature and pressure systems slightly less than and greater than supercritical water conditions can be used for the efficient destruction of waste biological treatment plant sludges, acetic acid, 2-nitro phenol, 2,4-dimethyl phenol, phenol, and 2,4-dinitro toluene. Above 400 °C, near complete destruction of sludge and transformation compounds such as acetic acid can be achieved with relatively short residence times. Ammonia and acetic acid are transformation products in the SCWO of biological treatment plant sludges. Acetic acid produced from the oxidation of sludge is oxidized rapidly at supercritical temperatures, 400 °C to 450 °C.


Author(s):  
Fumitake Takahashi ◽  
Zhirong Sun ◽  
Kensuke Fukushi ◽  
Yoshito Oshima ◽  
Kazuo Yamamoto

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