Three-Dimensional Porous Hexagonal Boron Nitride Fibers as Metal-Free Catalysts with Enhanced Catalytic Activity for Oxidative Dehydrogenation of Propane

2021 ◽  
Author(s):  
Guangming Wang ◽  
Yao Yan ◽  
Xuefei Zhang ◽  
Xinhua Gao ◽  
Zailai Xie
Keyword(s):  
Catalytic Activity ◽  
Boron Nitride ◽  
Oxidative Dehydrogenation ◽  
Hexagonal Boron Nitride ◽  
Three Dimensional ◽  
Oxidative Dehydrogenation Of Propane ◽  
Metal Free

scholarly journals It's a Gas: Oxidative Dehydrogenation of Propane over Boron Nitride Catalysts

2020 ◽  
Author(s):  
Peter Kraus ◽  
R. Peter Lindstedt
Keyword(s):  
Low Temperature ◽  
Boron Nitride ◽  
Gas Phase ◽  
Oxidative Dehydrogenation ◽  
Hexagonal Boron Nitride ◽  
Combustion Model ◽  
Low Temperature Combustion ◽  
Oxidative Dehydrogenation Of Propane ◽  
Temperature Combustion

We investigate the role of gas-phase phenomena in the heterogeneous oxidative dehydrogenation of propane over hexagonal boron nitride. We apply a recently developed gas-phase combustion model for low-temperature combustion of propane and couple it with several surface microkinetic mechanisms to probe the selectivity limits using the open-source flame solver Cantera. We show that while the conversion of propane is surface-driven, the selectivities are significantly influenced by the gas-phase, especially when dilute catalyst beds are used.<br>

O2 Activation and Oxidative Dehydrogenation of Propane on Hexagonal Boron Nitride: Mechanism Revisited

2019 ◽  
Vol 123 (4) ◽  
pp. 2256-2266 ◽  
Author(s):  
Hongping Li ◽  
Jinrui Zhang ◽  
Peiwen Wu ◽  
Suhang Xun ◽  
Wei Jiang ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Oxidative Dehydrogenation ◽  
Hexagonal Boron Nitride ◽  
Oxidative Dehydrogenation Of Propane ◽  
O2 Activation

Three dimensional nanocomposite of reduced graphene oxide and hexagonal boron nitride as an efficient metal-free catalyst for oxygen electroreduction

2016 ◽  
Vol 4 (12) ◽  
pp. 4506-4515 ◽  
Author(s):  
Indrajit M. Patil ◽  
Moorthi Lokanathan ◽  
Bhalchandra Kakade
Keyword(s):  
Graphene Oxide ◽  
Boron Nitride ◽  
Reduced Graphene Oxide ◽  
Hexagonal Boron Nitride ◽  
Three Dimensional ◽  
Oxygen Electroreduction ◽  
Onset Potential ◽  
Metal Free ◽  
Reduced Graphene ◽  
Orr Kinetics

Excellent ORR kinetics by an h-BN/rGO nanocomposite is shown with an onset potential ∼0.8 V vs. RHE, attributed to the segregation mechanism and coalescence of graphitic planes of h-BN and rGO.

scholarly journals It's a Gas: Oxidative Dehydrogenation of Propane over Boron Nitride Catalysts

2021 ◽  
Author(s):  
Peter Kraus ◽  
R. Peter Lindstedt
Keyword(s):  
Low Temperature ◽  
Boron Nitride ◽  
Gas Phase ◽  
Oxidative Dehydrogenation ◽  
Hexagonal Boron Nitride ◽  
Combustion Model ◽  
Low Temperature Combustion ◽  
Oxidative Dehydrogenation Of Propane ◽  
Temperature Combustion

We investigate the role of gas-phase phenomena in the heterogeneous oxidative dehydrogenation of propane over hexagonal boron nitride. We apply a recently developed gas-phase combustion model for low-temperature combustion of propane and couple it with several surface microkinetic mechanisms to probe the selectivity limits using the open-source flame solver Cantera. We show that while the conversion of propane is surface-driven, the selectivities are significantly influenced by the gas-phase, especially when dilute catalyst beds are used.<br>

scholarly journals It's a Gas: Oxidative Dehydrogenation of Propane over Boron Nitride Catalysts

2021 ◽  
Author(s):  
Peter Kraus ◽  
R. Peter Lindstedt
Keyword(s):  
Low Temperature ◽  
Boron Nitride ◽  
Gas Phase ◽  
Oxidative Dehydrogenation ◽  
Hexagonal Boron Nitride ◽  
Combustion Model ◽  
Low Temperature Combustion ◽  
Oxidative Dehydrogenation Of Propane ◽  
Temperature Combustion

We investigate the role of gas-phase phenomena in the heterogeneous oxidative dehydrogenation of propane over hexagonal boron nitride. We apply a recently developed gas-phase combustion model for low-temperature combustion of propane and couple it with several surface microkinetic mechanisms to probe the selectivity limits using the open-source flame solver Cantera. We show that while the conversion of propane is surface-driven, the selectivities are significantly influenced by the gas-phase, especially when dilute catalyst beds are used.<br>

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