A Comprehensive Review on Low-Temperature Combustion Technologies for Emission Reduction in Diesel Engines

Diesel engines are lean burn engines; hence CO and HC emissions in the exhaust are less likely to occur in substantial amounts. The emissions of serious concern in compression ignition engines are particulate matter and nitrogen oxides because of elevated temperature conditions of combustion. Hence the researchers have strived continuously to lower down the temperature of combustion in order to bring down the emissions from CI engines. This has been tried through premixed charge compression ignition, homogeneous charge compression ignition (HCCI), gasoline compression ignition and reactivity controlled compression ignition (RCCI). In this study, an attempt has been made to critically review the literature on low-temperature combustion conditions using various conventional and alternative fuels. The problems and challenges augmented with the strategies have also been described. Water-in-diesel emulsion technology has been discussed in detail. Most of the authors agree over the positive outcomes of water-diesel emulsion for both performance and emissions simultaneously.

Autoxidation of terpenes, a common pathway in tropospheric and low temperature combustion conditions: the case of limonene and α-pinene

The oxidation of monoterpenes under atmospheric conditions has been the subject of numerous studies. They were motivated by the formation of oxidized organic molecules (OOM) which, due to their low vapor pressure, contribute to the formation of secondary organic aerosols (SOA). Among the different reaction mechanisms proposed for the formation of these oxidized chemical compounds, it appears that the autoxidation mechanism, involving successive events of H-migration and O2 addition, common to both low-temperature combustion and atmospheric conditions, is leading to the formation of highly oxidized molecules (HOM). In atmospheric chemistry, the importance of autoxidation compared to other oxidation pathways has been the topic of numerous studies. Conversely, in combustion, autoxidation under cool flame conditions is the main oxidation process commonly taken into account. An analysis of oxidation products detected in both conditions was performed, using the present combustion data and literature data from tropospheric oxidation studies, to investigate possible similarities in terms of observed chemical formulae of products. To carry out this study, we chose two terpenes, α-pinene and limonene (C10H16), among the most abundant biogenic components in the atmosphere, and considered in many previous studies. Also, these two isomers were selected for the diversity of their reaction sites (exo- and endo- carbon-carbon double bonds). We built an experimental database consisting of literature atmospheric oxidation data and presently obtained combustion data for the oxidation of the two selected terpenes. In order to probe the effects of the type of ionization used in mass spectrometry analyses on the detection of oxidation products, we used heated electrospray ionization (HESI) and atmospheric pressure chemical ionization (APCI), in positive and negative modes. The oxidation of limonene-oxygen-nitrogen and α-pinene-oxygen-nitrogen mixtures was performed using a jet-stirred reactor at elevated temperature (590 K), a residence time of 2 s, and atmospheric pressure. Samples of the reacting mixtures were collected in acetonitrile and analyzed by high-resolution mass spectrometry (Orbitrap Q-Exactive) after direct injection and soft ionization, i.e. (+/−) HESI and (+/−) APCI. This work shows a surprisingly similar set of chemical formulae of products, including oligomers, formed in cool flames and under simulated atmospheric conditions. Data analysis showed that a non-negligible subset of chemical formulae is common to all experiments independently of experimental parameters. Finally, this study indicates that more than 40 % of the detected chemical formulae in this full dataset can be ascribed to an autoxidation mechanism.