Oxyfunctionalization of Alkanes Based on a Tricobalt(II)-Substituted Dawson-Type Rhenium Carbonyl Derivative as Catalyst

We synthesized a new phosphotungstate-supported rhenium carbonyl derivative, [N(CH3)4]6H4[P2W17O62{Re(CO)3}2]·25H2O, existing the first {Re2} fragment. Moreover, it also exhibits high efficiency for the selective oxidation of thiophenes.

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Synthesis, characterization and catalytic epoxidation properties of a new tellurotungstate(iv)-supported rhenium carbonyl derivative

Dalton Transactions ◽

10.1039/c8dt04195d ◽

2019 ◽

Vol 48 (2) ◽

pp. 628-634 ◽

Cited By ~ 7

Author(s):

Jingkun Lu ◽

Xinyi Ma ◽

Ping Wang ◽

Junwei Feng ◽

Pengtao Ma ◽

...

Keyword(s):

Catalytic Activity ◽

Reaction Conditions ◽

Carbonyl Derivative ◽

Catalytic Epoxidation ◽

Rhenium Carbonyl ◽

Epoxidation Of Alkenes

We synthesized a new tellurotungstate(iv)-supported rhenium carbonyl derivative, Na2H2[(CH3)4N]6[Te2W20O70{Re(CO)3}2]·20H2O (1). Additionally, compound 1 showed excellent catalytic activity in the selective epoxidation of alkenes under comparatively mild reaction conditions.

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Synthesis and Characterization of Novel Re(BIAN)(CO)3Cl Derivatives Including the First Example of a Water-soluble Tricarbonyl Rhenium(I) Complex with Bis(imino)acenaphthene Ligands

Zeitschrift für Naturforschung B ◽

10.5560/znb.2014-4016 ◽

2014 ◽

Vol 69 (6) ◽

pp. 691-698 ◽

Cited By ~ 5

Author(s):

Elham Kianfar ◽

Uwe Monkowius ◽

Engelbert Portenkirchner ◽

Günther Knör

Keyword(s):

Water Soluble ◽

Spectroscopic Techniques ◽

Ortho Position ◽

The Novel ◽

Carbonyl Derivative ◽

Chloride Complexes ◽

Carbonyl Chloride ◽

Rhenium Carbonyl ◽

Halide Ligand

A series of rhenium(I) carbonyl chloride complexes carrying bis(imino)acenaphthene (BIAN) molecules as p-acceptor ligands was prepared and characterized by various spectroscopic techniques. Among the novel compounds described, the remarkable example of a deeply colored water-soluble rhenium carbonyl derivative is presented. The crystal structures of this family of BIAN compounds are also reported, which confirm the position of the chloro ligand at the tricarbonyl rhenium(I) center. In the case of BIAN ligands carrying bulky substituents in the ortho-position of the arylimino subunits, evidence has been found for an exchange of the halide ligand in solution, which is considered to be of major relevance for catalytic applications. Implications of our results for the fields of photocatalytic CO2 reduction and the controlled release of the gasotransmitter CO in aqueous solution are briefly discussed.

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An isotetramolybdate-supported rhenium carbonyl derivative: synthesis, characterization, and use as a catalyst for sulfoxidation

Dalton Transactions ◽

10.1039/c8dt00429c ◽

2018 ◽

Vol 47 (15) ◽

pp. 5279-5285 ◽

Cited By ~ 15

Author(s):

Jingkun Lu ◽

Xinyi Ma ◽

Vikram Singh ◽

Yujiao Zhang ◽

Pengtao Ma ◽

...

Keyword(s):

Catalytic Activity ◽

Selective Oxidation ◽

Reaction Conditions ◽

Carbonyl Derivative ◽

Oxidation Of Sulfides ◽

Rhenium Carbonyl

We successfully synthesized an isotetramolybdate-supported rhenium carbonyl derivative, [(CH3)4N]4[{Re(CO)3}4(Mo4O16)]·H2O, which showed excellent catalytic activity in the selective oxidation of sulfides under comparatively mild reaction conditions.

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Correction: A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes

CrystEngComm ◽

10.1039/c9ce90187f ◽

2020 ◽

Vol 22 (3) ◽

pp. 610-610

Author(s):

Jingkun Lu ◽

Junwei Feng ◽

Xinyi Ma ◽

Ping Wang ◽

Baijie Xu ◽

...

Keyword(s):

Selective Oxidation ◽

Carbonyl Derivative ◽

Rhenium Carbonyl ◽

Catalytic Selective Oxidation

Correction for ‘A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes’ by Jingkun Lu et al., CrystEngComm, 2019, 21, 7322–7328.

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