An isotetramolybdate-supported rhenium carbonyl derivative: synthesis, characterization, and use as a catalyst for sulfoxidation

2018 ◽  
Vol 47 (15) ◽  
pp. 5279-5285 ◽  
Author(s):  
Jingkun Lu ◽  
Xinyi Ma ◽  
Vikram Singh ◽  
Yujiao Zhang ◽  
Pengtao Ma ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Selective Oxidation ◽  
Reaction Conditions ◽  
Carbonyl Derivative ◽  
Oxidation Of Sulfides ◽  
Rhenium Carbonyl

We successfully synthesized an isotetramolybdate-supported rhenium carbonyl derivative, [(CH3)4N]4[{Re(CO)3}4(Mo4O16)]·H2O, which showed excellent catalytic activity in the selective oxidation of sulfides under comparatively mild reaction conditions.

Synthesis, characterization and catalytic epoxidation properties of a new tellurotungstate(iv)-supported rhenium carbonyl derivative

2019 ◽  
Vol 48 (2) ◽  
pp. 628-634 ◽  
Author(s):  
Jingkun Lu ◽  
Xinyi Ma ◽  
Ping Wang ◽  
Junwei Feng ◽  
Pengtao Ma ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Reaction Conditions ◽  
Carbonyl Derivative ◽  
Catalytic Epoxidation ◽  
Rhenium Carbonyl ◽  
Epoxidation Of Alkenes

We synthesized a new tellurotungstate(iv)-supported rhenium carbonyl derivative, Na2H2[(CH3)4N]6[Te2W20O70{Re(CO)3}2]·20H2O (1). Additionally, compound 1 showed excellent catalytic activity in the selective epoxidation of alkenes under comparatively mild reaction conditions.

A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7322-7328 ◽  
Author(s):  
Jingkun Lu ◽  
Junwei Feng ◽  
Xinyi Ma ◽  
Ping Wang ◽  
Baijie Xu ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
High Efficiency ◽  
Carbonyl Derivative ◽  
Rhenium Carbonyl ◽  
Catalytic Selective Oxidation

We synthesized a new phosphotungstate-supported rhenium carbonyl derivative, [N(CH3)4]6H4[P2W17O62{Re(CO)3}2]·25H2O, existing the first {Re2} fragment. Moreover, it also exhibits high efficiency for the selective oxidation of thiophenes.

Anderson polyoxometalate built-in covalent organic frameworks for enhancing catalytic performances

2020 ◽  
Vol 8 (17) ◽  
pp. 8548-8553 ◽  
Author(s):  
Rui Ma ◽  
Naifang Liu ◽  
Ting-Ting Lin ◽  
Tianbo Zhao ◽  
Sheng-Li Huang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Selective Oxidation ◽  
Covalent Organic Frameworks ◽  
Oxidation Of Sulfides ◽  
Catalytic Performances

Anderson polyoxometalate-based covalent organic frameworks exhibited the highest catalytic activity in the photodegradation of RhB and MB, as well as 100% selective oxidation of sulfides to sulfoxides.

Nano-Au/C Catalysts for the Selective Oxidation of Glucose into Gluconate

2011 ◽  
Vol 412 ◽  
pp. 235-238
Author(s):  
Zi Jing Li ◽  
Du Shu Huang ◽  
Wei Liu ◽  
Rui Min Xiao ◽  
Jie Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Carbon Support ◽  
Reaction Conditions ◽  
Gold Particles ◽  
Gold Sol ◽  
Citrate Reduction ◽  
Oxidation Of Glucose

Au/C catalyst used for the liquid phase selective oxidation of glucose to gluconate was prepared by gold sol method that includes the preparation of metallic colloid by citrate reduction and subsequent immersion by carbon support. The influence of gold particles of different size on the activity of Au/C catalyst was studied. The results show that the catalyst with good dispersed spherical gold particles has higher catalytic activity. After 16 runs, the conversion of glucose selective oxidation can still achieve over 96% under mild reaction conditions.

scholarly journals Correction: A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes

CrystEngComm ◽  
2020 ◽  
Vol 22 (3) ◽  
pp. 610-610
Author(s):  
Jingkun Lu ◽  
Junwei Feng ◽  
Xinyi Ma ◽  
Ping Wang ◽  
Baijie Xu ◽  
...  
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Derivative ◽  
Rhenium Carbonyl ◽  
Catalytic Selective Oxidation

Correction for ‘A new phosphotungstate-supported rhenium carbonyl derivative: synthesis, characterization and catalytic selective oxidation of thiophenes’ by Jingkun Lu et al., CrystEngComm, 2019, 21, 7322–7328.

Ni-SMTU@boehmite: as an efficient and recyclable nanocatalyst for oxidation reactions

RSC Advances ◽  
2016 ◽  
Vol 6 (61) ◽  
pp. 56458-56466 ◽  
Author(s):  
Arash Ghorbani-Choghamarani ◽  
Parisa Moradi ◽  
Bahman Tahmasbi
Keyword(s):  
Catalytic Activity ◽  
Selective Oxidation ◽  
Nickel Catalyst ◽  
Oxidative Coupling ◽  
Oxidation Reactions ◽  
Oxidation Of Sulfides ◽  
Boehmite Nanoparticles ◽  
Organometallic Catalyst

An efficient heterogenized nickel catalyst on boehmite nanoparticles was synthesized and characterized. The catalytic activity of this organometallic catalyst was examined in the selective oxidation of sulfides and oxidative coupling of thiols.

scholarly journals Ring-Opening Copolymerization of Cyclohexene Oxide and Cyclic Anhydrides Catalyzed by Bimetallic Scorpionate Zinc Catalysts

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1651
Author(s):  
Felipe de la Cruz-Martínez ◽  
Marc Martínez de Sarasa Buchaca ◽  
Almudena del Campo-Balguerías ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Reaction Mechanism ◽  
Catalytic System ◽  
Phthalic Anhydride ◽  
Ring Opening ◽  
High Selectivity ◽  
Zinc Complexes ◽  
Cyclohexene Oxide ◽  
Reaction Conditions ◽  
Cyclic Anhydrides

The catalytic activity and high selectivity reported by bimetallic heteroscorpionate acetate zinc complexes in ring-opening copolymerization (ROCOP) reactions involving CO2 as substrate encouraged us to expand their use as catalysts for ROCOP of cyclohexene oxide (CHO) and cyclic anhydrides. Among the catalysts tested for the ROCOP of CHO and phthalic anhydride at different reaction conditions, the most active catalytic system was the combination of complex 3 with bis(triphenylphosphine)iminium as cocatalyst in toluene at 80 °C. Once the optimal catalytic system was determined, the scope in terms of other cyclic anhydrides was broadened. The catalytic system was capable of copolymerizing selectively and efficiently CHO with phthalic, maleic, succinic and naphthalic anhydrides to afford the corresponding polyester materials. The polyesters obtained were characterized by spectroscopic, spectrometric, and calorimetric techniques. Finally, the reaction mechanism of the catalytic system was proposed based on stoichiometric reactions.

Enhanced catalytic activity over MIL-100(Fe) with coordinatively unsaturated Fe2+/Fe3+ sites for selective oxidation of H2S to sulfur

2019 ◽  
Vol 374 ◽  
pp. 793-801 ◽  
Author(s):  
Xiaoxiao Zheng ◽  
Linyan Zhang ◽  
Zhangjia Fan ◽  
Yanning Cao ◽  
Lijuan Shen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Selective Oxidation
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