P2S5 Reactive Flux Method for the Rapid Synthesis of Mono- and Bimetallic 2D Thiophosphates M2–xM′xP2S6

2021 ◽  
Vol 60 (6) ◽  
pp. 3502-3513
Author(s):  
Daniel G. Chica ◽  
Abishek K. Iyer ◽  
Matthew Cheng ◽  
Kevin M. Ryan ◽  
Patrick Krantz ◽  
...  
1995 ◽  
Vol 102 (1) ◽  
pp. 104-118 ◽  
Author(s):  
Sabine K. Reese ◽  
Susan C. Tucker ◽  
Gregory K. Schenter

APL Materials ◽  
2015 ◽  
Vol 3 (10) ◽  
pp. 104413 ◽  
Author(s):  
Xianglin Zhu ◽  
Zeyan Wang ◽  
Baibiao Huang ◽  
Wei Wei ◽  
Ying Dai ◽  
...  

1994 ◽  
Vol 180 (2-3) ◽  
pp. 167-180 ◽  
Author(s):  
Diane E. Sagnella ◽  
Jianshu Cao ◽  
Gregory A. Voth

2019 ◽  
Vol 75 (7) ◽  
pp. 1041-1045
Author(s):  
Lotfi Rghioui ◽  
Lahcen El Ammari ◽  
Abderrazzak Assani ◽  
Mohamed Saadi

The crystal structures of dirubidium potassium dysprosium bis(vanadate), Rb2KDy(VO4)2, and caesium potassium gadolinium bis(vanadate), Cs1.52K1.48Gd(VO4)2, were solved from single-crystal X-ray diffraction data. Both compounds, synthesized by the reactive flux method, crystallize in the space group P\overline{3}m1 with the glaserite structure type. VO4 tetrahedra are linked to DyO6 or GdO6 octahedra by common vertices to form sheets stacking along the c axis. The large twelve-coordinate Cs+ or Rb+ cations are sandwiched between these layers in tunnels along the a and b axes, while the K+ cations, surrounded by ten oxygen atoms, are localized in cavities.


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