Purely Spectroscopic Determination of the Spin Hamiltonian Parameters in High-Spin Six-Coordinated Cobalt(II) Complexes with Large Zero-Field Splitting

Inorganic Chemistry ◽

10.1021/acs.inorgchem.9b02195 ◽

2019 ◽

Vol 58 (24) ◽

pp. 16434-16444 ◽

Author(s):

Eugenii Ya. Misochko ◽

Alexander V. Akimov ◽

Denis V. Korchagin ◽

Joscha Nehrkorn ◽

Mykhaylo Ozerov ◽

...

Keyword(s):

High Spin ◽

Spectroscopic Determination ◽

Spin Hamiltonian ◽

Zero Field Splitting ◽

Field Splitting ◽

Hamiltonian Parameters

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Definitive Spectroscopic Determination of Zero-Field Splitting in High-Spin Cobalt(II)

Journal of the American Chemical Society ◽

10.1021/ja039257y ◽

2004 ◽

Vol 126 (7) ◽

pp. 2148-2155 ◽

Author(s):

J. Krzystek ◽

S. A. Zvyagin ◽

Andrew Ozarowski ◽

Adam T. Fiedler ◽

Thomas C. Brunold ◽

...

Keyword(s):

High Spin ◽

Spectroscopic Determination ◽

Zero Field Splitting ◽

Field Splitting

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EPR spectroscopy of soybean lipoxygenase-1 Determination of the zero-field splitting constants of high-spin Fe(III) signals from temperature and microwave frequency dependence

Biochimica et Biophysica Acta (BBA) - Protein Structure ◽

10.1016/0005-2795(80)90222-6 ◽

1980 ◽

Vol 624 (1) ◽

pp. 30-39 ◽

Author(s):

Steven Slappendel ◽

Gerrit A. Veldink ◽

Johannes F.G. Vliegenthart ◽

Roland Aasa ◽

Bo G. Malmström

Keyword(s):

Frequency Dependence ◽

High Spin ◽

Epr Spectroscopy ◽

Microwave Frequency ◽

Soybean Lipoxygenase ◽

Zero Field Splitting ◽

Field Splitting

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Determination of the zero-field splitting constants of high-spin metalloproteins by a continuous-wave microwave saturation technique

Journal of Magnetic Resonance (1969) ◽

10.1016/0022-2364(82)90140-8 ◽

1982 ◽

Vol 46 (2) ◽

pp. 247-256 ◽

Author(s):

Moon B Yim ◽

Lawrence C Kuo ◽

Marvin W Makinen

Keyword(s):

High Spin ◽

Continuous Wave ◽

Zero Field Splitting ◽

Field Splitting

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Multi-frequency EPR determination of zero field splitting of high spin species in liquids: Gd(III) chelates in water

Molecular Physics ◽

10.1080/00268979809483262 ◽

1998 ◽

Vol 95 (6) ◽

pp. 1325-1332 ◽

Author(s):

R. B. CLARKSON ◽

ALEX I. SMIRNOV ◽

T. I. SMIRNOVA ◽

H. KANG ◽

R. L. BELFORD ◽

...

Keyword(s):

High Spin ◽

Zero Field Splitting ◽

Field Splitting ◽

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Determination of zero-field splitting and evidence for the presence of charge-transfer transitions in the Soret region of high-spin ferric hemoproteins obtained from an analysis of low-temperature magnetic circular dichroism

Biochimica et Biophysica Acta (BBA) - Protein Structure and Molecular Enzymology ◽

10.1016/s0167-4838(98)00228-3 ◽

1998 ◽

Vol 1429 (1) ◽

pp. 163-175 ◽

Author(s):

Vasily S. Oganesyan ◽

Yuri A. Sharonov

Keyword(s):

Charge Transfer ◽

Low Temperature ◽

High Spin ◽

Magnetic Circular Dichroism ◽

Zero Field Splitting ◽

Field Splitting ◽

Charge Transfer Transitions ◽

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Optical Spectroscopic Determination of the Zero‐Field Splitting in Vibronic Levels of the Triplet State of Nitrite

The Journal of Chemical Physics ◽

10.1063/1.1675282 ◽

1971 ◽

Vol 54 (7) ◽

pp. 2979-2981 ◽

Author(s):

Robin M. Hochstrasser ◽

Ahmed H. Zewail

Keyword(s):

Triplet State ◽

Spectroscopic Determination ◽

Zero Field Splitting ◽

Field Splitting

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EPR studies on the high spin FeIII tetraphenylporphine with rhombic character, determination of zero-field splitting parameters from the middle kramers transition

Chemical Physics ◽

10.1016/0301-0104(76)87057-7 ◽

1976 ◽

Vol 12 (2) ◽

pp. 199-211 ◽

Author(s):

Mitsuo Sato ◽

Hideo Kon

Keyword(s):

High Spin ◽

Zero Field Splitting ◽

Field Splitting

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Determination of Large Zero-Field Splitting in High-Spin Co(I) Clathrochelates

Inorganic Chemistry ◽

10.1021/acs.inorgchem.8b02670 ◽

2018 ◽

Vol 57 (24) ◽

pp. 15330-15340 ◽

Author(s):

Joscha Nehrkorn ◽

Sergey L. Veber ◽

Liudmila A. Zhukas ◽

Valentin V. Novikov ◽

Yulia V. Nelyubina ◽

...

Keyword(s):

High Spin ◽

Zero Field Splitting ◽

Field Splitting

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Theoretical studies of the spin-Hamiltonian parameters and the effects of the temperature and pressure on the zero-field splitting for Ni2+: Zn(BF4)2·6H2O crystal

Physica B Condensed Matter ◽

10.1016/j.physb.2006.03.027 ◽

2007 ◽

Vol 387 (1-2) ◽

pp. 52-55 ◽

Author(s):

Wen-Lin Feng ◽

Wen-Chen Zheng ◽

Xiao-Xuan Wu ◽

Hong-Gang Liu

Keyword(s):

Theoretical Studies ◽

Spin Hamiltonian ◽

Zero Field Splitting ◽

Field Splitting ◽

Temperature And Pressure ◽

Hamiltonian Parameters

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ESR SPECTRUM OF Fe+3 IN TOPAZ: I. FINE STRUCTURE

Canadian Journal of Physics ◽

10.1139/p67-303 ◽

1967 ◽

Vol 45 (11) ◽

pp. 3597-3610 ◽

Author(s):

J. R. Thyer ◽

S. M. Quick ◽

F. Holuj

Keyword(s):

Fine Structure ◽

Spin Hamiltonian ◽

Zero Field Splitting ◽

Field Splitting ◽

Esr Spectrum ◽

Hamiltonian Parameters ◽

Near Future ◽

ESR spectrum of Fe+3 in topaz (Al2SiO4F2) has been investigated at X- and K-band frequencies. The spectrum, in addition to large zero-field splitting, also shows well-resolved h.f.s. due to 19F at some orientations. The spin-Hamiltonian parameters, which include b21 and b41, are given in the text. The spectrum has been interpreted to originate from Fe+3 impurity located at Al+3 sites. The implications of these results are considered briefly. The results of the analysis of the h.f.s. are to be published in the near future.

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