Excess Molar Volume and Viscosity Deviation of [C2mim][NTf2]/[C4mim][NTf2] + DMC/DEC

2018 ◽  
Vol 63 (12) ◽  
pp. 4484-4496 ◽  
Author(s):  
Qingshan Liu ◽  
Liwei Zhao ◽  
Qige Zheng ◽  
Lin Mou ◽  
Pengfei Zhang
Keyword(s):  
Molar Volume ◽  
Excess Molar Volume ◽  
Viscosity Deviation

Density, Viscosity, Excess Molar Volume, and Viscosity Deviation of Three Amyl Alcohols + Ethanol Binary Mixtures from 293.15 to 323.15 K

2006 ◽  
Vol 51 (3) ◽  
pp. 940-945 ◽  
Author(s):  
Estrella Álvarez ◽  
Ángeles Cancela ◽  
Rocío Maceiras ◽  
José M. Navaza ◽  
Rubén Táboas
Keyword(s):  
Molar Volume ◽  
Binary Mixtures ◽  
Excess Molar Volume ◽  
Viscosity Deviation

scholarly journals Excess Molar Volume Calculation and Viscosity Deviation and Excess Gibbs Energy for Binary Solution of 1- Propanol with Butyl Acetate at Temperatures (40,50,60) 0C

2019 ◽  
Vol 27 (2) ◽  
pp. 295-305
Author(s):  
Zaher Al haddad ◽  
Mahmoud Amer
Keyword(s):  
Free Energy ◽  
Molar Volume ◽  
Gibbs Free Energy ◽  
Excess Molar Volume ◽  
Butyl Acetate ◽  
Binary Solution ◽  
Excess Molar Volumes ◽  
Excess Gibbs Free Energy ◽  
Viscosity Deviation ◽  
Deviation In Viscosity

In this research, the solubility Process of the binary liquid solution(1-Propanol and butyl acetate) were studied at temperature(40,50.60)0C. Densities ρ by pycnometer method and viscosity ƞ by OSTWALD tube that calibrated with distilled water was measured. Then excess molar volume was calculated of pure component and its mixtures that was prepared over the entire mole fraction range. It has been observed that excess molar volumes values were negative at all temperatures. After that, the deviation in viscosity ∆ ƞ  and Excess Gibbs free energy ∆GE was determined and it has been observed that it takes negative values at all temperatures. Excess molar volume, deviation in viscosity, excess Gibbs free energy were correlated with Redlich-Kister equation Type polynomial and the showed an accepted standard deviation between the experimental and calculated values it has been shown the effect of Hydrogen bonds formation and the spherical shape for the molecules and its size on the excess thermodynamic properties.

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