Latent Nucleophilic Carbenes

We report the first preparation of a N-alkoxyimidazolylidene (NOHC), a nucleophilic carbene based on an oxidized imidazolium core. The carbene carbon shows the highest upfield 13C NMR shift compared to...

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Reactions of thiocarbonyl compounds with electrophilic and nucleophilic carbenes as well as with their metal complexes

Journal of Sulfur Chemistry ◽

10.1080/17415993.2020.1780237 ◽

2020 ◽

Vol 41 (6) ◽

pp. 672-700

Author(s):

Grzegorz Mlostoń ◽

Heinz Heimgartner

Keyword(s):

Metal Complexes ◽

Nucleophilic Carbenes

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Basicity of Nucleophilic Carbenes in Aqueous and Nonaqueous SolventsTheoretical Predictions

Journal of the American Chemical Society ◽

10.1021/ja038973x ◽

2004 ◽

Vol 126 (28) ◽

pp. 8717-8724 ◽

Cited By ~ 301

Author(s):

Alison M. Magill ◽

Kingsley J. Cavell ◽

Brian F. Yates

Keyword(s):

Nucleophilic Carbenes

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Nucleophilic Carbenes as Organocatalysts

Ernst Schering Foundation Symposium Proceedings - Organocatalysis ◽

10.1007/2789_2008_081 ◽

2008 ◽

pp. 203-225 ◽

Cited By ~ 2

Author(s):

F. Glorius ◽

K. Hirano

Keyword(s):

Nucleophilic Carbenes

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Redox-state dependent activation of silanes and ammonia with reverse polarity (PCcarbeneP)Ni complexes: electrophilic vs. nucleophilic carbenes

Dalton Transactions ◽

10.1039/c8dt04409k ◽

2018 ◽

Vol 47 (46) ◽

pp. 16789-16797 ◽

Cited By ~ 15

Author(s):

Etienne A. LaPierre ◽

Warren E. Piers ◽

Chris Gendy

Keyword(s):

Redox State ◽

Nickel Complexes ◽

Synthesis And Characterization ◽

Reverse Polarity ◽

Nucleophilic Carbenes ◽

State Dependent

A rigidified PCalkylP ligand allowed for the synthesis and characterization of cationic and radical PCCarbeneP nickel complexes in which the carbene anchor of the pincer framework is electrophilic rather than nucleophilic.

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