Temperature Dependence of the Rate of Intramolecular Electron Transfer

2018 ◽  
Vol 122 (38) ◽  
pp. 8824-8833 ◽  
Author(s):  
William W. Parson
Keyword(s):  
Electron Transfer ◽  
Temperature Dependence ◽  
Intramolecular Electron Transfer

Superexchange in the fast lane – intramolecular electron transfer in a molecular triad occurs by conformationally gated superexchange

2019 ◽  
Vol 55 (36) ◽  
pp. 5251-5254 ◽  
Author(s):  
Yusen Luo ◽  
Maria Wächtler ◽  
Kevin Barthelmes ◽  
Andreas Winter ◽  
Ulrich S. Schubert ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Temperature Dependence ◽  
Photoinduced Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Fast Lane

Photoinduced electron transfer via hopping is generally considered to have a stronger temperature dependence than electron transfer via superexchange.

Intramolecular Electron Transfer Mediated by a Tetrathiafulvalene Bridge in a Purely Organic Mixed-Valence System

2003 ◽  
Vol 42 (24) ◽  
pp. 2765-2768 ◽  
Author(s):  
Nicolas Gautier ◽  
Frédéric Dumur ◽  
Vega Lloveras ◽  
José Vidal-Gancedo ◽  
Jaume Veciana ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
Intramolecular Electron Transfer

scholarly journals Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

2016 ◽  
Vol 45 (43) ◽  
pp. 17104-17107 ◽  
Author(s):  
Rong-Jia Wei ◽  
Ryohei Nakahara ◽  
Jamie M. Cameron ◽  
Graham N. Newton ◽  
Takuya Shiga ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Spin Transition ◽  
Intramolecular Electron Transfer ◽  
Thermally Induced ◽  
Trigonal Bipyramidal ◽  
Transition Behaviour

A cyanide-bridged trigonal bipyramidal [Co3Fe2] cluster shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition behaviour.

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