Kinetic Selectivity of Lithium Alkyl Carbonate Formation from Combination Reactions of Ethylene Carbonate Radical Anions

2020 ◽  
Vol 124 (47) ◽  
pp. 25754-25759
Author(s):  
Mathew J. Boyer ◽  
Gyeong S. Hwang
Keyword(s):  
Ethylene Carbonate ◽  
Radical Anions ◽  
Carbonate Radical ◽  
Carbonate Formation ◽  
Kinetic Selectivity

scholarly journals On the incompatibility of lithium–O2 battery technology with CO2

2017 ◽  
Vol 8 (9) ◽  
pp. 6117-6122 ◽  
Author(s):  
Shiyu Zhang ◽  
Matthew J. Nava ◽  
Gary K. Chow ◽  
Nazario Lopez ◽  
Gang Wu ◽  
...  
Keyword(s):  
Reactive Species ◽  
Organic Media ◽  
Radical Anions ◽  
Carbonate Radical ◽  
Battery Technology

The peroxide dianion reacts with CO2 in polar aprotic organic media to afford the hydroperoxycarbonate and carbonate radical anions. These highly reactive species, if formed in lithium–O2 cells, can lead to cell degradation via oxidation of the electrolyte and electrode.

Oxidation of Guanine and 8-oxo-7,8-Dihydroguanine by Carbonate Radical Anions: Insight from Oxygen-18 Labeling Experiments

2005 ◽  
Vol 117 (32) ◽  
pp. 5185-5188 ◽  
Author(s):  
Conor Crean ◽  
Nicholas E. Geacintov ◽  
Vladimir Shafirovich
Keyword(s):  
Radical Anions ◽  
Carbonate Radical

A selectivity study of reaction of the carbonate radical anion with methyl β-d-cellobioside and methyl β-d-glucoside in oxygenated aqueous solutions

Holzforschung ◽  
2006 ◽  
Vol 60 (2) ◽  
pp. 130-136 ◽  
Author(s):  
Magnus Carlsson ◽  
Johan Lind ◽  
Gábor Merényi
Keyword(s):  
Radical Anion ◽  
Hydrogen Abstraction ◽  
Radical Anions ◽  
Bleaching Agent ◽  
Hydrogen Atoms ◽  
Carbonate Radical ◽  
Abstraction Reaction ◽  
Carbonate Radical Anion ◽  
Hydrogen Abstraction Reaction

Abstract In the presence of oxygen, radiolytically generated carbonate radical anions, CO3 •–, were reacted with methyl β-D-cellobioside and methyl β-D-glucoside. From the ensuing product pattern, it was concluded that CO3 •– abstracts hydrogen atoms predominantly from glucosidic C1–H bonds. This high intramolecular selectivity was rationalised mainly in terms of a polar effect on the transition state of the hydrogen abstraction reaction. The present findings are in sharp contrast to the relative inertness of CO3 •– towards glucosidic C1–H bonds previously observed in cotton linters. The reasons for this discrepancy are discussed in light of a possible future role of CO3 •– as a bleaching agent for pulp.

Sign in / Sign up

Export Citation Format

Share Document