First-Principles Study of Amorphous Al2O3 ALD Coating in Li-S Battery Electrode Design

The Li-S battery is exceptionally appealing as an alternative candidate beyond Li-ion battery technology due to its promising high specific energy capacity. However, several obstacles (e.g., polysulfides’ dissolution, shuttle effect, high volume expansion of cathode, etc.) remain and thus hinder the commercialization of the Li-S battery. To overcome these challenges, a fundamental study based on atomistic simulation could be very useful. In this work, a comprehensive investigation of the adsorption of electrolyte (solvent and salt) molecules, lithium sulfide, and polysulfide (Li2Sx with 2 ≤x≤ 8) molecules on the amorphous Al2O3 atomic layer deposition (ALD) surface was performed using first-principles density functional theory (DFT) calculations. The DFT results indicate that the amorphous Al2O3 ALD surface is selective in chemical adsorption towards lithium sulfide and polysulfide molecules compared to electrolytes. Based on this work, it suggests that the Al2O3 ALD is a promising coating material for Li-S battery electrodes to mitigate the shuttling problem of soluble polysulfides.

A flame-retardant polyimide interlayer with polysulfide lithium traps and fast redox conversion towards safety and high sulfur utilization Li-S batteries

In recent years and following the progress made in lithium-ion battery technology, substantial efforts have been devoted to developing practical lithium-sulfur (Li–S) batteries for next-generation commercial energy storage devices. The...

Advancements in Battery Technologies of Electric Vehicle

The Automotive Industry has undergone a huge revolution – Electric Vehicles! Electric cars are growing fast and the demand for them is increasing all around the world, thanks to the more and improved choice, reduced prices, and enhancing battery technology. Introduced more than 100 years ago, electric vehicles have gone through a tremendous amount of advancement. This paper reviews the current major challenges faced by the Electric Vehicle Industry along with possible solutions to overcome them. Although electric vehicles have come a long way, the battery used in the vehicles needs to be further explored to harness maximum energy with a compact design. Electric vehicles should soon be able to compete with combustion engine vehicles in every aspect. Also, this paper reviews alternative materials for electrodes and batteries to make charging faster and reliable than ever. This paper envisages few concepts that could revolutionize Automobile Industry further in the future.

2021 Edward G. Weston Fellowship - Summary Report: Layered Sodium Manganese Oxide as a Versatile Battery Cathode for Insertion of Monovalent Ions (Li+, Na+, and K+) in Non-aqueous Electrolytes

The transition from fossil fuels to carbon-free forms of renewable energy has become a spotlight with the revolutionary emergence of efficient electrochemical energy storage systems. It enables us to realize electric mobility empowered by Li-ion battery technology. Nevertheless, for the past three decades, the development of battery technology has been very sluggish, and it warrants new strategies to meet the growing demand for high energy density. In this spirit, we are working to develop versatile battery cathodes, which can be used for electrochemical and electrocatalytic applications.

Battery Management System in Electric Vehicles

Here this document provides the data about the batteries of electric vehicles. It consists of numerous data about various energy storage methods in EVs and how it is different from energy storage of IC-engine vehicles. How electric vehicles will take over ICEngine vehicles due to advancement in battery technology and the shrink in its prices. Various types of batteries are listed in the document with their specifications. Possible future battery technology which will have more or same energy density than current gasoline fuels and also with the significant reduction in battery weights; which will make EVs cheaper than current condition. Some examples are listed showing current battery capacities of various EVs models. Some battery parameters are shown in the document with introduction to BMS (Battery Management System). Then a brief introduction about the charging of these EV batteries and its types displaying variations in charging time in different types of EVs according to their charger type and manufacturers. How DC charging is more time saving method than AC and how smart charging will help to grid in case of peak or grid failure conditions.

Computer Simulation Design of Electric Vehicle Dynamic Performance

New energy vehicles are mainly pure electric new energy vehicles. Pure electric vehicles are powered entirely by batteries, as well as power generators. With the improvement of economic level, scientific and technological progress, as well as the emphasis on energy conservation and emission reduction, the development of pure electric vehicles is more rapid, computer simulation design technology helps to adjust and optimize the dynamic performance of electric vehicles, in 2019, the output of pure electric vehicles reached 56,700, it is expected to reach about 100,000 by 2022. However, due to the limitation of battery technology, the average range of pure electric vehicles is about 200km. So it can only withstand short distances between cities.

Development and Progression of Polymer Electrolytes for Batteries: Influence of Structure and Chemistry

Polymer electrolytes continue to offer the opportunity for safer, high-performing next-generation battery technology. The benefits of a polymeric electrolyte system lie in its ease of processing and flexibility, while ion transport and mechanical strength have been highlighted for improvement. This report discusses how factors, specifically the chemistry and structure of the polymers, have driven the progression of these materials from the early days of PEO. The introduction of ionic polymers has led to advances in ionic conductivity while the use of block copolymers has also increased the mechanical properties and provided more flexibility in solid polymer electrolyte development. The combination of these two, ionic block copolymer materials, are still in their early stages but offer exciting possibilities for the future of this field.

Photochemically driven solid electrolyte interphase for extremely fast-charging lithium-ion batteries

Extremely fast charging (i.e. 80% of storage capacity within 15 min) is a pressing requirement for current lithium-ion battery technology and also affects the planning of charging infrastructure. Accelerating lithium ion transport through the solid-electrolyte interphase (SEI) is a major obstacle in boosting charging rate; in turn, limited kinetics at the SEI layer negatively affect the cycle life and battery safety as a result of lithium metal plating on the electrode surface. Here, we report a γ-ray-driven SEI layer that allows a battery cell to be charged to 80% capacity in 10.8 min as determined for a graphite full-cell with a capacity of 2.6 mAh cm−2. This exceptional charging performance is attributed to the lithium fluoride-rich SEI induced by salt-dominant decomposition via γ-ray irradiation. This study highlights the potential of non-electrochemical approaches to adjust the SEI composition toward fast charging and long-term stability, two parameters that are difficult to improve simultaneously in typical electrochemical processes owing to the trade-off relation.

Electrochemical Preparation of Nano-Sized Silicon as a Lithium-Ion Battery Anode Material

Highly pure silicon is an important component in photovoltaic applications and has potential in battery technology. In this study, the electrochemical behavior of Si (IV) was discussed in a NaF−LiF−Na2SiO3−SiO2 electrolyte at 750 °C , and lithium-ion battery performance with electrodeposited silicon powder as anode material were investigated. The cyclic voltammograms illustrated that the reduction of Si(IV) on an Ag electrode followed an irreversible two-step, two-electron process: Si(IV) → Si(II) and Si(II) → Si(0). Both reduction steps involved diffusion control, and the diffusion coefficients were 1.18 and 1.22 × 10−6 cm2/s, respectively. Nanoscale spherical silicon was deposited between potentials of −1.0 to −1.6 V (vs. Pt) with support of X-ray diffraction patterns, Raman spectra, and scanning electron microscopy analysis. Combining the fabricated silicon with carbon, a Si@C composite anode material for lithium-ion batteries was prepared, and its specific capacity reached 1260 mAh/g. Notably, a capacity of 200 mAh/g was maintained over 100 cycles.