scholarly journals Modeling Interfacial Electron Transfer in the Double Layer: The Interplay between Electrode Coupling and Electrostatic Driving

2019 ◽  
Vol 124 (2) ◽  
pp. 1352-1361 ◽  
Author(s):  
Aditya M. Limaye ◽  
Adam P. Willard
Keyword(s):  
Electron Transfer ◽  
Double Layer ◽  
Interfacial Electron Transfer

scholarly journals Modeling Interfacial Electron Transfer in the Double Layer: The Interplay Between Electrode Coupling and Electrostatic Driving

2019 ◽  
Author(s):  
Aditya Limaye ◽  
Adam Willard
Keyword(s):  
Electron Transfer ◽  
Double Layer ◽  
Electrical Potential ◽  
Potential Drop ◽  
Active Species ◽  
Transfer Reactions ◽  
Electronic Coupling ◽  
Interfacial Electron Transfer ◽  
Redox Active ◽  
Solvent Polarization

This manuscript presents a theoretical model for simulating interfacial electron transfer reactions within the electrical double layer. This model resolves the population density of redox active species and simulated electron transfer at the level of Marcus theory, with a fluctuating solvent polarization coordinate. In this model, the kinetics and thermodynamics of electron transfer depend on the values of the electronic coupling of species (to the electrode) and the electrical potential drop, respectively.

scholarly journals Modeling Interfacial Electron Transfer in the Double Layer: The Interplay Between Electrode Coupling and Electrostatic Driving

2019 ◽  
Author(s):  
Aditya Limaye ◽  
Adam Willard
Keyword(s):  
Electron Transfer ◽  
Double Layer ◽  
Electrical Potential ◽  
Potential Drop ◽  
Active Species ◽  
Transfer Reactions ◽  
Electronic Coupling ◽  
Interfacial Electron Transfer ◽  
Redox Active ◽  
Solvent Polarization

This manuscript presents a theoretical model for simulating interfacial electron transfer reactions within the electrical double layer. This model resolves the population density of redox active species and simulated electron transfer at the level of Marcus theory, with a fluctuating solvent polarization coordinate. In this model, the kinetics and thermodynamics of electron transfer depend on the values of the electronic coupling of species (to the electrode) and the electrical potential drop, respectively.

A Comparison between Interfacial Electron-Transfer Rate Constants at Metallic and Graphite Electrodes

2006 ◽  
Vol 110 (39) ◽  
pp. 19433-19442 ◽  
Author(s):  
William J. Royea ◽  
Thomas W. Hamann ◽  
Bruce S. Brunschwig ◽  
Nathan S. Lewis
Keyword(s):  
Electron Transfer ◽  
Rate Constants ◽  
Transfer Rate ◽  
Interfacial Electron Transfer ◽  
Electron Transfer Rate ◽  
Graphite Electrodes

Autonomous Control of Interfacial Electron Transfer and the Activation of DNA Machines by an Oscillatory pH System

Nano Letters ◽  
2013 ◽  
Vol 13 (10) ◽  
pp. 4920-4924 ◽  
Author(s):  
Xiu-Juan Qi ◽  
Chun-Hua Lu ◽  
Xiaoqing Liu ◽  
Simcha Shimron ◽  
Huang-Hao Yang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Autonomous Control ◽  
Interfacial Electron Transfer ◽  
Dna Machines

Interfacial electron transfer in titanium dioxide colloids

1985 ◽  
Vol 107 (23) ◽  
pp. 6446-6451 ◽  
Author(s):  
Graham T. Brown ◽  
James R. Darwent ◽  
Paul D. I. Fletcher
Keyword(s):  
Electron Transfer ◽  
Titanium Dioxide ◽  
Interfacial Electron Transfer
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