Voltage-Induced Bistability of Single Spin-Crossover Molecules in a Two-Dimensional Monolayer

2021 ◽  
pp. 11029-11034
Author(s):  
Yongfeng Tong ◽  
Massine Kelaï ◽  
Kaushik Bairagi ◽  
Vincent Repain ◽  
Jérôme Lagoute ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Two Dimensional ◽  
Single Spin

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

Atomically Thin Two-Dimensional Nanosheets with Tunable Spin-Crossover Properties

2018 ◽  
Vol 9 (24) ◽  
pp. 7052-7058 ◽  
Author(s):  
Yang-Hui Luo ◽  
Chen Chen ◽  
Guo-Wei Lu ◽  
Dan-Li Hong ◽  
Xiao-Tong He ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Two Dimensional

Two-Step Spin-Crossover with Three Inequivalent FeII Sites in a Two-Dimensional Hofmann-Type Coordination Polymer

2017 ◽  
Vol 23 (42) ◽  
pp. 10034-10037 ◽  
Author(s):  
Yan Meng ◽  
Qing-Qing Sheng ◽  
Md. Najbul Hoque ◽  
Yan-Cong Chen ◽  
Si-Guo Wu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Two Dimensional

Spin-Crossover Phenomenon in Microcrystals and Nanoparticles of a [Fe(2-mpz)2Ni(CN)4] Two-Dimensional Hofmann-Type Polymer: A Detailed Nano-Topographic Study

2019 ◽  
Vol 58 (20) ◽  
pp. 13733-13736 ◽  
Author(s):  
Christina D. Polyzou ◽  
Ondřej Malina ◽  
Jiri Tuček ◽  
Radek Zbořil ◽  
Nikos Panagiotou ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Two Dimensional

An Investigation of Photo- and Pressure-Induced Effects in a Pair of Isostructural Two-Dimensional Spin-Crossover Framework Materials

2014 ◽  
Vol 20 (24) ◽  
pp. 7448-7457 ◽  
Author(s):  
Natasha F. Sciortino ◽  
Suzanne M. Neville ◽  
Cédric Desplanches ◽  
Jean-François Létard ◽  
Victor Martinez ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Two Dimensional ◽  
Framework Materials

scholarly journals Four-step iron(ii) spin state cascade driven by antagonistic solid state interactions

2017 ◽  
Vol 8 (1) ◽  
pp. 701-707 ◽  
Author(s):  
Natasha F. Sciortino ◽  
Katrina A. Zenere ◽  
Maggie E. Corrigan ◽  
Gregory J. Halder ◽  
Guillaume Chastanet ◽  
...  
Keyword(s):  
Solid State ◽  
Spin State ◽  
Spin Crossover ◽  
Type Material ◽  
Two Dimensional ◽  
Crossover Transition

A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.

scholarly journals Two-Dimensional Nanoscale Imaging of Gadolinium Spins via Scanning Probe Relaxometry with a Single Spin in Diamond

2014 ◽  
Vol 2 (5) ◽  
Author(s):  
M. Pelliccione ◽  
B. A. Myers ◽  
L. M. A. Pascal ◽  
A. Das ◽  
A. C. Bleszynski Jayich
Keyword(s):  
Scanning Probe ◽  
Two Dimensional ◽  
Single Spin ◽  
Nanoscale Imaging

scholarly journals Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework

2016 ◽  
Vol 55 (22) ◽  
pp. 11652-11661 ◽  
Author(s):  
Eric Milin ◽  
Véronique Patinec ◽  
Smail Triki ◽  
El-Eulmi Bendeif ◽  
Sébastien Pillet ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Addressing single spin crossover molecules in a two-dimensional monolayer

2021 ◽  
Author(s):  
Yongfeng Tong ◽  
Massine Kelaï ◽  
Kaushik Bairagi ◽  
Vincent Repain ◽  
Jérôme Lagoute ◽  
...  
Keyword(s):  
Spin State ◽  
Single Molecule ◽  
Spin Crossover ◽  
Cooperative Behaviour ◽  
Spintronic Devices ◽  
Single Spin ◽  
Elastic Interactions ◽  
Molecular Spin ◽  
External Stimuli ◽  
At Will

Abstract Bistable spin-crossover molecules are particularly interesting to the development of innovative electronic and spintronic devices as they present two spin states that can be controlled by external stimuli. In this purpose, being able to switch at will the spin state of a single molecule in a dense molecular array is a key milestone. However, the elastic interactions between the molecules favour more cooperative behaviour where patches of neighbouring molecules switches simultaneously. We demonstrate here that the interaction of iron II spin-crossover molecules with a metallic substrate can strongly reduce their cooperative behaviour until addressing independently single molecular spin state. Mechanoelastic model is able to reproduce well such findings.

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