Spin Crossover in the {Fe(pz)[Pt(CN)4]} Metal–Organic Framework upon Pyrazine Adsorption

2016 ◽  
Vol 7 (19) ◽  
pp. 4022-4026 ◽  
Author(s):  
C. Huy Pham ◽  
Francesco Paesani
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Guest Modulation of Spin-Crossover Transition Temperature in a Porous Iron(II) Metal-Organic Framework: Experimental and Periodic DFT Studies

2014 ◽  
Vol 20 (40) ◽  
pp. 12864-12873 ◽  
Author(s):  
Daniel Aravena ◽  
Zulema Arcís Castillo ◽  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
Ko Yoneda ◽  
...  
Keyword(s):  
Transition Temperature ◽  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Iron ◽  
Dft Studies ◽  
Metal Organic ◽  
Crossover Transition ◽  
Periodic Dft ◽  
Organic Framework

Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework

2012 ◽  
Vol 124 (40) ◽  
pp. 10301-10305 ◽  
Author(s):  
Natasha F. Sciortino ◽  
Katrin R. Scherl-Gruenwald ◽  
Guillaume Chastanet ◽  
Gregory J. Halder ◽  
Karena W. Chapman ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Inside Cover: Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework (Angew. Chem. Int. Ed. 40/2012)

2012 ◽  
Vol 51 (40) ◽  
pp. 9944-9944 ◽  
Author(s):  
Natasha F. Sciortino ◽  
Katrin R. Scherl-Gruenwald ◽  
Guillaume Chastanet ◽  
Gregory J. Halder ◽  
Karena W. Chapman ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate

2016 ◽  
Vol 40 (11) ◽  
pp. 9012-9016 ◽  
Author(s):  
Il'ya A. Gural'skiy ◽  
Sergii I. Shylin ◽  
Bohdan O. Golub ◽  
Vadim Ksenofontov ◽  
Igor O. Fritsky ◽  
...  
Keyword(s):  
High Temperature ◽  
Spin Crossover ◽  
Metal Organic Framework ◽  
Spin Transition ◽  
Thermally Induced ◽  
Metal Organic ◽  
Organic Framework

Thermally induced spin transition at 370 K has been observed in a Hofmann-clathrate-like metal–organic framework.

scholarly journals Elastic Frustration Triggering Photoinduced Hidden Hysteresis and Multistability in a Two-Dimensional Photoswitchable Hofmann-Like Spin-Crossover Metal–Organic Framework

2016 ◽  
Vol 55 (22) ◽  
pp. 11652-11661 ◽  
Author(s):  
Eric Milin ◽  
Véronique Patinec ◽  
Smail Triki ◽  
El-Eulmi Bendeif ◽  
Sébastien Pillet ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

Asymmetric seven-/eight-step spin-crossover in a three-dimensional Hofmann-type metal–organic framework

2020 ◽  
Vol 7 (8) ◽  
pp. 1685-1690 ◽  
Author(s):  
Yuan-Yuan Peng ◽  
Si-Guo Wu ◽  
Yan-Cong Chen ◽  
Wei Liu ◽  
Guo-Zhang Huang ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Crossover Behavior ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

An unprecedented hysteretic seven-/eight-step spin-crossover behavior is revealed. Most importantly, a molecular alloy based on a Hofmann-type framework is used as a strategy to explore multi-step spin-crossover materials for the first time.

scholarly journals A spin crossover porous hybrid architecture for potential sensing applications

2019 ◽  
Vol 55 (2) ◽  
pp. 194-197 ◽  
Author(s):  
Antoine Tissot ◽  
Xavier Kesse ◽  
Styliani Giannopoulou ◽  
Ingrid Stenger ◽  
Laurent Binet ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Hybrid Architecture ◽  
Sensing Applications ◽  
Metal Organic ◽  
Organic Framework

Spin crossover cations have been successfully synthesized in the pores of a mesoporous robust Metal–Organic Framework (MOF) MIL-100(Al) through sequential introduction of Fe(iii) cations and a sal2trien ligand.

Four-step spin-crossover in an oxamide-decorated metal-organic framework

2021 ◽  
Author(s):  
Siguo Wu ◽  
Sukhen Bala ◽  
Zeyu Ruan ◽  
Guozhang Huang ◽  
Zhaoping Ni ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Perturbation of Spin Crossover Behavior by Covalent Post-Synthetic Modification of a Porous Metal-Organic Framework

2014 ◽  
Vol 53 (38) ◽  
pp. 10164-10168 ◽  
Author(s):  
John E. Clements ◽  
Jason R. Price ◽  
Suzanne M. Neville ◽  
Cameron J. Kepert
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

Reversible three equal-step spin crossover in an iron(ii) Hofmann-type metal–organic framework

2018 ◽  
Vol 47 (5) ◽  
pp. 1407-1411 ◽  
Author(s):  
Fu-Ling Liu ◽  
Dong Li ◽  
Li-Jie Su ◽  
Jun Tao
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Crossover Behavior ◽  
Metal Organic ◽  
Organic Framework

A novel bent ligand-pillared 3D Hofmann-type MOF exhibited incomplete three-step spin-crossover behavior with a sequence of HS1.00 ↔ HS0.75LS0.25 ↔ HS0.5LS0.5 ↔ HS0.25LS0.75.

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