N–H and C–H Bond Activations of an Isoindoline Promoted by Iridium- and Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols

: Dess–Martin periodinane (DMP), is a commercially available chemical, frequently being utilized as a mild oxidative agent for the selective oxidation of primary and secondary alcohols to their corresponding aldehydes and ketones, respectively. DMP shows several merits over other common oxidative agent such as chromium- and DMSO-based oxidants, thus it is habitually employed in the total synthesis of natural products. In this review, we try to underscore the applications of DMP as an effective oxidant in an appropriate step (steps) in the multistep total synthesis of natural products.

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Oxidations with chromium(VI) oxide. VII. The mechanism of oxidation of secondary alcohols

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19582068 ◽

1958 ◽

Vol 23 (11) ◽

pp. 2068-2080 ◽

Cited By ~ 26

Author(s):

J. Roček ◽

J. Krupička

Keyword(s):

Secondary Alcohols ◽

Chromium Vi ◽

Mechanism Of Oxidation

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Oxidation rates of triterpenoid secondary alcohols with chromic acid

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19760770 ◽

1976 ◽

Vol 41 (3) ◽

pp. 770-779 ◽

Cited By ~ 3

Author(s):

M. R. Nair ◽

S. Hilgard ◽

J. Klinot ◽

K. Waisser ◽

A. Vystrčil

Keyword(s):

Chromic Acid ◽

Secondary Alcohols ◽

Oxidation Rates

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Simple theoretical models of elimination reactions on polar catalysts; Dehydration reactivity of secondary alcohols on acidic and basic catalysts

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19850920 ◽

1985 ◽

Vol 50 (4) ◽

pp. 920-929 ◽

Cited By ~ 1

Author(s):

Jiří Sedláček

Keyword(s):

Experimental Data ◽

Quantum Chemical ◽

Theoretical Models ◽

Aliphatic Alcohols ◽

Secondary Alcohols ◽

Carbonium Ion ◽

Dehydration Reactions ◽

Aromatic Alcohols ◽

Basic Catalysts ◽

Simple Models

CNDO/2 calculations for simple models of adsorption and dehydration reactions of secondary aliphatic and aromatic alcohols on polar catalysts are presented. The models involve selected stages of elimination mechanisms of various types (E1, E2 and E1cB elimination). Calculated quantum chemical quantities were correlated with reported experimental data. It is shown that reactivities for the series of substituted phenylethanols correlate very well with the ease of carbonium ion formation. In the case of aliphatic alcohols, calculated quantities correlate generally with the reactivities on SiO2 and are in anticorrelation with the reactivities on Al2O3.NaOH.

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Luminescent nucleotide/Tb3+ coordination polymer for Fe(ii) detection in human serum

Analytical Methods ◽

10.1039/c9ay02585e ◽

2020 ◽

Vol 12 (8) ◽

pp. 1122-1130

Author(s):

Yan Liu ◽

Lu-Lu Peng ◽

Wei-Xiong Huang ◽

Hui-Zhuo Zhou ◽

Li Xu

Keyword(s):

Coordination Polymer ◽

Human Serum ◽

Adenosine Triphosphate ◽

High Sensitivity ◽

Sensitivity And Selectivity ◽

Bridge Ligand

A luminescent nucleotide/Tb3+ coordination polymer (CP) was synthesized using adenosine triphosphate (ATP) molecules as a bridge ligand and Phen as a sensitizer, which showed high sensitivity and selectivity for Fe2+.

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