Visible-Light-Mediated Construction of Pyrroloindolines via an Amidyl Radical Cyclization/Carbon Radical Addition Cascade: Rapid Synthesis of (±)-Flustramide B

2017 ◽  
Vol 19 (20) ◽  
pp. 5669-5672 ◽  
Author(s):  
Kui Wu ◽  
Yuliu Du ◽  
Ting Wang
Keyword(s):  
Visible Light ◽  
Radical Addition ◽  
Radical Cyclization ◽  
Rapid Synthesis

Visible-light-facilitated P-center radical addition to C=X (X = C, N) bonds results in cyclizations

2021 ◽  
Author(s):  
Shang-Dong Yang ◽  
Chong Li ◽  
Juan Wang
Keyword(s):  
Visible Light ◽  
Organophosphorus Compounds ◽  
Radical Addition ◽  
Radical Reactions

Visible-light-facilitated phosphorus radical reactions have been developed as a powerful and sustainable tool for the synthesis of various organophosphorus compounds. In general, these reactions require stoichiometric amounts of oxidants, and...

Synthesis of Isoquinoline-1,3(2H,4H)-diones by Visible-light-mediated the Cyclization of Acryloylbenzamides with Alkyl Boronic Acids, Arylsulfonylhydrazides and Oxime Esters

Synthesis ◽  
2022 ◽  
Author(s):  
Jiahui Fu ◽  
Xingxing Cai ◽  
Yihuo Liu ◽  
Jing-Hua Li ◽  
Dongping Cheng ◽  
...  
Keyword(s):  
Visible Light ◽  
Bioactive Compounds ◽  
Boronic Acids ◽  
Radical Addition ◽  
Tandem Reaction ◽  
Good Opportunity ◽  
Mild Conditions ◽  
Reaction Proceeds

An efficient visible-light-mediated tandem reaction of acryloylbenzamides with alkyl boronic acids, arylsulfonylhydrazides and oxime esters is developed. The reaction proceeds the radical addition and cyclization to give various isoquinoline-1,3(2H,4H)-diones in satisfactory yields under mild conditions, which provides a good opportunity to discover new meaningful bioactive compounds.

Transition metal-free, visible-light-mediated construction of α,β-diamino esters via decarboxylative radical addition at room temperature

2019 ◽  
Vol 6 (13) ◽  
pp. 2245-2249 ◽  
Author(s):  
Guibing Wu ◽  
Jingwen Wang ◽  
Chengyu Liu ◽  
Maolin Sun ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Visible Light ◽  
Carboxylic Acids ◽  
Room Temperature ◽  
Radical Addition ◽  
Metal Free ◽  
Radical Coupling

A metal-free photoredox catalyzed decarboxylative radical coupling of free-carboxylic acids and glyoxylic oximes was developed to synthesize α,β-diamino acids.

Visible-light-mediated radical cascade reaction: synthesis of 3-bromocoumarins from alkynoates

2017 ◽  
Vol 15 (41) ◽  
pp. 8820-8826 ◽  
Author(s):  
Shangbiao Feng ◽  
Jinlai Li ◽  
Zaimin Liu ◽  
Haiyu Sun ◽  
Hongliang Shi ◽  
...  
Keyword(s):  
Visible Light ◽  
Cascade Reaction ◽  
Radical Addition ◽  
Reaction Synthesis ◽  
Radical Cascade

The development of a visible-light mediated bromo radical addition/spirocyclization/ester migration cascade reaction to generate 3-bromocoumarins from alkynoates is reported.

A practical synthesis of benzothiophenes via visible-light-promoted cyclization of disulfides and alkynes

2017 ◽  
Vol 15 (3) ◽  
pp. 550-554 ◽  
Author(s):  
Lin-Miao Ye ◽  
Lu Qian ◽  
Yan-Yan Chen ◽  
Xue-Jing Zhang ◽  
Ming Yan
Keyword(s):  
Visible Light ◽  
Radical Cyclization ◽  
Practical Synthesis

Visible-light-promoted radical cyclization of disulfides and alkynes provided benzothiophenes in good yields.

Synthesis of Gem-Difluorinated Fused Quinolines via Visible Light-Mediated Cascade Radical Cyclization

2016 ◽  
Vol 18 (5) ◽  
pp. 1004-1007 ◽  
Author(s):  
Tiebo Xiao ◽  
Linyong Li ◽  
Yang Xie ◽  
Zong-Wan Mao ◽  
Lei Zhou
Keyword(s):  
Visible Light ◽  
Radical Cyclization

Visible-light-induced radical cyclization of N-allylbenzamides with CF3SO2Na to trifluoromethylated dihydroisoquinolinones in water at room temperature

2019 ◽  
Vol 21 (12) ◽  
pp. 3362-3369 ◽  
Author(s):  
Long Zou ◽  
Pinhua Li ◽  
Bin Wang ◽  
Lei Wang
Keyword(s):  
Visible Light ◽  
Room Temperature ◽  
Radical Cyclization ◽  
Efficient Strategy

An efficient strategy for the preparation of trifluoromethylated dihydroisoquinolinones via visible-light induced radical cyclization of N-allylbenzamides with CF3SO2Na was developed.

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