Pillared Metal–Organic Framework Initiating Intermolecular Atom-Transfer Radical Addition via Visible-Light-Induced Electron Transfer Activation of Haloalkanes

Author(s):  
Xin Liu ◽  
Zhifen Guo ◽  
Yan Che ◽  
Rong Bai ◽  
Yanhong Chi ◽  
...  
RSC Advances ◽  
2018 ◽  
Vol 8 (57) ◽  
pp. 32610-32620 ◽  
Author(s):  
Tiexin Zhang ◽  
Pengfang Wang ◽  
Zirui Gao ◽  
Yang An ◽  
Cheng He ◽  
...  

Iodoperfluoroalkylation or (Z)-selective perfluoroalkylation of olefins is mediated through energy transfer processes by using pyrene-based MOF NU-1000 under visible-light irradiation.


2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.


2021 ◽  
Author(s):  
Zhen Han ◽  
Yaomei Fu ◽  
Yingchao Zhang ◽  
Xiao Zhang ◽  
Xing Meng ◽  
...  

We designed and synthesized TVPT-MOFs, combined with g-C3N4, and the yield of CO2 reduction could reach 56 μmol·g−1·h−1.


2021 ◽  
Vol 4 (4) ◽  
pp. 4037-4047
Author(s):  
Muhammad Bilal Hussain ◽  
Rashid Mehmood ◽  
Umair Azhar ◽  
Junnuan Wang ◽  
Lianghao Song

2020 ◽  
Vol 56 (44) ◽  
pp. 5929-5932 ◽  
Author(s):  
Peng Li ◽  
Qi Sui ◽  
Meng-Yue Guo ◽  
Shuai-Liang Yang ◽  
Ran Bu ◽  
...  

The MOF provides unique confined space furnished with electron acceptor sites, and exposure to amines/alcohols causes specific and size-selective direct/UV-assisted color change owing to spontaneous/photoinduced electron transfer.


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