In Situ Room-Temperature Cross-Linked Highly Branched Biopolymeric Binder Based on the Diels–Alder Reaction for High-Performance Silicon Anodes in Lithium-Ion Batteries

2021 ◽  
Author(s):  
Zhixiang Cai ◽  
Shanming Hu ◽  
Yue Wei ◽  
Tao Huang ◽  
Aishui Yu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Room Temperature ◽  
Lithium Ion ◽  
Alder Reaction ◽  
Diels Alder ◽  
Silicon Anodes ◽  
Diels Alder Reaction

Mechanically Robust and Superior Conductive n-Type Polymer Binders for High-performance Micro-Silicon Anodes in Lithium-Ion Batteries

2021 ◽  
Author(s):  
Yuanyuan Yu ◽  
Jiadeng Zhu ◽  
Ke Zeng ◽  
Mengjin Jiang
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
Silicon Anodes ◽  
Polymer Binders ◽  
Nanostructured Silicon

Abstract text goes here. The abstract should be a single paragraph that summarises the content of the article Compared with nanostructured silicon (Si), Si microparticle (SiMP) has more commercial prospects...

scholarly journals Hetero-Diels–Alder reactions of hetaryl and aryl thioketones with acetylenic dienophiles

2015 ◽  
Vol 11 ◽  
pp. 576-582 ◽  
Author(s):  
Grzegorz Mlostoń ◽  
Paulina Grzelak ◽  
Maciej Mikina ◽  
Anthony Linden ◽  
Heinz Heimgartner
Keyword(s):  
High Pressure ◽  
Room Temperature ◽  
Thermal Conditions ◽  
Alder Reaction ◽  
Diels Alder ◽  
Hydrogen Shift ◽  
Diels Alder Reaction ◽  
Shift Sequence

Selected hetaryl and aryl thioketones react with acetylenecarboxylates under thermal conditions in the presence of LiClO4 or, alternatively, under high-pressure conditions (5 kbar) at room temperature yielding thiopyran derivatives. The hetero-Diels–Alder reaction occurs in a chemo- and regioselective manner. The initially formed [4 + 2] cycloadducts rearrange via a 1,3-hydrogen shift sequence to give the final products. The latter were smoothly oxidized by treatment with mCPBA to the corresponding sulfones.

scholarly journals Ternary NiCoP nanoparticles assembled on graphene for high-performance lithium-ion batteries and supercapacitors

RSC Advances ◽  
2017 ◽  
Vol 7 (42) ◽  
pp. 26120-26124 ◽  
Author(s):  
Chunde Wang ◽  
Yinyin Qian ◽  
Jing Yang ◽  
Shiqi Xing ◽  
Xu Ding ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Room Temperature ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Solution Phase ◽  
Phase Method ◽  
Self Assembled ◽  
Solution Phase Method

We demonstrate that ternary NiCoP nanoparticles can be self-assembled on graphene at room temperature by a solution-phase method and our electrode materials exhibit a high performance for LIBs and supercapacitors.

High performance epoxy coating with cross-linkable solvent via Diels-Alder reaction for anti-corrosion of concrete

2020 ◽  
Vol 139 ◽  
pp. 105473 ◽  
Author(s):  
Jinfeng Chi ◽  
Guoliang Zhang ◽  
Qingyi Xie ◽  
Chunfeng Ma ◽  
Guangzhao Zhang
Keyword(s):  
High Performance ◽  
Alder Reaction ◽  
Diels Alder ◽  
Epoxy Coating ◽  
Diels Alder Reaction

scholarly journals Enhancing the reactivity of 1,2-diphospholes in cycloaddition reactions

2015 ◽  
Vol 11 ◽  
pp. 169-173 ◽  
Author(s):  
Almaz Zagidullin ◽  
Vasili Miluykov ◽  
Elena Oshchepkova ◽  
Artem Tufatullin ◽  
Olga Kataeva ◽  
...  
Keyword(s):  
Room Temperature ◽  
Cycloaddition Reaction ◽  
Alder Reaction ◽  
Diels Alder ◽  
Alkyl Halides ◽  
Ethyl Iodide ◽  
Para Position ◽  
Cycloaddition Reactions ◽  
Diels Alder Reaction ◽  
Heating Up

Two different approaches have been employed to enhance the reactivity of 1-alkyl-1,2-diphospholes – the introduction of electron-withdrawing groups either at the phosphorus atoms or in the para-position of the arene ring. The alkylation of sodium 1,2-diphospha-3,4,5-triphenylcyclopentadienide with alkyl halides Hal-CH2-R (R = CN, COOEt, OMe, CH2OEt) results in corresponding 1-alkyl-3,4,5-triphenyl-1,2-diphospholes (alkyl = CH2CN (1a), CH2COOEt (1b), CH2OMe (1c), and (CH2)2OEt (1d)), which spontaneously undergo the intermolecular [4 + 2] cycloaddition reactions at room temperature to form the mixture of the cycloadducts, 2a–c, respectively. However the alkylation of sodium 1,2-diphospha-3,4,5-tri(p-fluorophenyl)cyclopentadienide with ethyl iodide leads to stable 1-ethyl-3,4,5-tris(p-fluorophenyl)-1,2-diphosphole (1e), which forms the [4 + 2] cycloadduct 2,3,4,4a,5,6-hexa(p-fluorophenyl)-1-ethyl-1,7,7a-triphospha-4,7-(ethylphosphinidene)indene (2e) only upon heating up to 60 °C. With further heating to 120 °C with N-phenylmaleimide, the cycloadducts 2a–c and 2e undergo the retro-Diels–Alder reaction and form only one product of the [4 + 2] cycloaddition reaction 3a–с, 3e with good yields up to 65%.

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