Multinuclear NMR Study of the Solid Electrolyte Interface Formed in Lithium Metal Batteries

2017 ◽  
Vol 9 (17) ◽  
pp. 14741-14748 ◽  
Author(s):  
Chuan Wan ◽  
Suochang Xu ◽  
Mary Y. Hu ◽  
Ruiguo Cao ◽  
Jiangfeng Qian ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Lithium Metal ◽  
Multinuclear Nmr ◽  
Lithium Metal Batteries ◽  
Electrolyte Interface ◽  
Nmr Study

Effects of Concentrated Salt and Resting Protocol on Solid Electrolyte Interface Formation for Improved Cycle Stability of Anode-Free Lithium Metal Batteries

2019 ◽  
Vol 11 (35) ◽  
pp. 31962-31971 ◽  
Author(s):  
Tamene Tadesse Beyene ◽  
Bikila Alemu Jote ◽  
Zewdu Tadesse Wondimkun ◽  
Bizualem Wakuma Olbassa ◽  
Chen-Jui Huang ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Cycle Stability ◽  
Lithium Metal ◽  
Interface Formation ◽  
Lithium Metal Batteries ◽  
Electrolyte Interface

Adhesive Sulfide Solid Electrolyte Interface for Lithium Metal Batteries

2020 ◽  
Vol 12 (49) ◽  
pp. 54876-54883
Author(s):  
Wei Jiang ◽  
Lijing Yan ◽  
Xiaomin Zeng ◽  
Xiangjuan Meng ◽  
Renzhi Huang ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Electrolyte Interface

Multinuclear NMR Study of the Solid Electrolyte Interface on the Li-FeSn2 Negative Electrodes for Li-Ion Batteries

2012 ◽  
Vol 116 (3) ◽  
pp. 2390-2398 ◽  
Author(s):  
Hua Huo ◽  
Mohamad Chamas ◽  
Pierre-Emmanuel Lippens ◽  
Michel Ménétrier
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Li Ion Batteries ◽  
Multinuclear Nmr ◽  
Electrolyte Interface ◽  
Nmr Study ◽  
Negative Electrodes ◽  
Li Ion

scholarly journals Constructing multifunctional solid electrolyte interface via in-situ polymerization for dendrite-free and low N/P ratio lithium metal batteries

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Dan Luo ◽  
Lei Zheng ◽  
Zhen Zhang ◽  
Matthew Li ◽  
Zhongwei Chen ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
In Situ Polymerization ◽  
Dendrite Growth ◽  
Solid Electrolyte Interface ◽  
Lithium Metal ◽  
Growth Orientation ◽  
Lithium Metal Batteries ◽  
Electrolyte Interface ◽  
Nucleation Growth

AbstractStable solid electrolyte interface (SEI) is highly sought after for lithium metal batteries (LMB) owing to its efficient electrolyte consumption suppression and Li dendrite growth inhibition. However, current design strategies can hardly endow a multifunctional SEI formation due to the non-uniform, low flexible film formation and limited capability to alter Li nucleation/growth orientation, which results in unconstrained dendrite growth and short cycling stability. Herein, we present a novel strategy to employ electrolyte additives containing catechol and acrylic groups to construct a stable multifunctional SEI by in-situ anionic polymerization. This self-smoothing and robust SEI offers multiple sites for Li adsorption and steric repulsion to constrain nucleation/growth process, leading to homogenized Li nanosphere formation. This isotropic nanosphere offers non-preferred Li growth orientation, rendering uniform Li deposition to achieve a dendrite-free anode. Attributed to these superiorities, a remarkable cycling performance can be obtained, i.e., high current density up to 10 mA cm−2, ultra-long cycle life over 8500 hrs operation, high cumulative capacity over 4.25 Ah cm−2 and stable cycling under 60 °C. A prolonged lifespan can also be achieved in Li-S and Li-LiFePO4 cells under lean electrolyte content, low N/P ratio or high temperature conditions. This facile strategy also promotes the practical application of LMB and enlightens the SEI design in related fields.

scholarly journals Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li10 GeP2 S12 Solid Electrolyte Interface

2018 ◽  
Vol 57 (41) ◽  
pp. 13608-13612 ◽  
Author(s):  
Yue Gao ◽  
Daiwei Wang ◽  
Yuguang C. Li ◽  
Zhaoxin Yu ◽  
Thomas E. Mallouk ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Lithium Metal ◽  
Electrolyte Interface ◽  
Inorganic Nanocomposites

scholarly journals Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li10 GeP2 S12 Solid Electrolyte Interface

2018 ◽  
Vol 130 (41) ◽  
pp. 13796-13800
Author(s):  
Yue Gao ◽  
Daiwei Wang ◽  
Yuguang C. Li ◽  
Zhaoxin Yu ◽  
Thomas E. Mallouk ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Solid Electrolyte Interface ◽  
Lithium Metal ◽  
Electrolyte Interface ◽  
Inorganic Nanocomposites
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