scholarly journals Photocatalytic and Ferric Ion Sensing Properties of a New Three-Dimensional Metal–Organic Framework Based on Cuboctahedral Secondary Building Units

ACS Omega ◽  
2019 ◽  
Vol 4 (6) ◽  
pp. 10775-10783 ◽  
Author(s):  
Qiongjie Ding ◽  
Ying Pan ◽  
Yingmei Luo ◽  
Mi Zhou ◽  
Yucheng Guan ◽  
...  
2015 ◽  
Vol 68 (1) ◽  
pp. 161 ◽  
Author(s):  
Zhuo-Wei Wang ◽  
Hui Zhao ◽  
Min Chen ◽  
Min Hu

Combination of a non-planar tripodal ligand 3,4-bi(4-carboxyphenyl)-benzoic acid (H3L) and Zn5O4-cluster secondary building units affords a highly connected three-dimensional metal–organic framework, {[Zn5(μ3-OH)3(μ2-OH)L2(H2O)2](H2O)2}n (1), which exhibits an unusual (3,4,9)-connected (42.5)(3.43.52)(32.45.511.613.73.82) topological net. The thermal stability and solid luminescence of the crystalline material have also been investigated.


2019 ◽  
Vol 48 (19) ◽  
pp. 6314-6318 ◽  
Author(s):  
Rika Ochi ◽  
Shin-ichiro Noro ◽  
Kazuya Kubo ◽  
Takayoshi Nakamura

A three-dimensional metal–organic framework with unprecedented [Zn2(N-oxide)2] secondary building units was synthesized using 3,5-pyridinedicarboxylic acid N-oxide.


2013 ◽  
Vol 834-836 ◽  
pp. 543-549
Author(s):  
Lei Wu ◽  
Ming Xue ◽  
Gérald Chaplais ◽  
Guang Shan Zhu ◽  
Shi Lun Qiu ◽  
...  

A novel 3D metal-organic framework based on tetranuclear copper Secondary Building Units, [Cu2(μ3-OH)(4-oip)(DMF)]·DMF·2H2O (JUC-76) (4-oip = 4-hydroxyisophthalic, DMF =N,N-dimethylformamide, and JUC = Jilin University China), has been synthesized under solvothermal conditions. It crystallizes in monoclinic symmetry with space groupP21/n. JUC-76 possesses a three-dimensional network with one-dimensional rhombic channels of approximately 13.6 × 8.5 Å2along the [100] direction. The resulting structure of JUC-76 is a distorted rutile topology with one 3-connected organic node and one 6-connected inorganic node. And its Schläfli symbol is (4·62)2(42·610·83). In addition, JUC-76 exhibits fluorescence emission at 446 nm, and a dominant anti-ferromagnetic interaction between the Cu (II) ions.


2017 ◽  
Vol 363 ◽  
pp. 103-109 ◽  
Author(s):  
Jiarui He ◽  
Weiqiang Lv ◽  
Yuanfu Chen ◽  
Jie Xiong ◽  
Kechun Wen ◽  
...  

2011 ◽  
Vol 14 (11) ◽  
pp. 1819-1822 ◽  
Author(s):  
Zhi-Hui Zhang ◽  
Sheng-Chun Chen ◽  
Qun Chen ◽  
Ming-Yang He ◽  
Huan Xu

2022 ◽  
Author(s):  
Julia G. Knapp ◽  
Debmalya Ray ◽  
Paul B. Calio ◽  
Megan C. Wasson ◽  
Thais R. Scott ◽  
...  

Competitive electron transitions are present in a rare three-dimensional Ce(iii)-catecholate metal–organic framework.


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