Syntheses, Structures, and Photoluminescences of Four Cd(II) Coordination Architectures Based on 1-(4-Pyridylmethyl)-2-methylimidazole and Aromatic Carboxylates: From One-Dimensional Chain to Three-Dimensional Coordination Architecture

2012 ◽  
Vol 12 (4) ◽  
pp. 2004-2012 ◽  
Author(s):  
Fu-Jing Liu ◽  
Hong-Jun Hao ◽  
Cheng-Jie Sun ◽  
Xiao-Hang Lin ◽  
Hao-Peng Chen ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Aromatic Carboxylates

The Helium Stockpile: A Collaboration in Mathematical Folding Sculpture

Leonardo ◽  
2006 ◽  
Vol 39 (3) ◽  
pp. 233-235 ◽  
Author(s):  
Eric D. Demaine ◽  
Martin L. Demaine ◽  
A. Laurie Palmer
Keyword(s):  
Three Dimensional ◽  
Dimensional Chain ◽  
Mathematical Basis ◽  
One Dimensional ◽  
Dimensional Shape ◽  
Folding Structure ◽  
Three Dimensional Shape

The Helium Stockpile is a manipulable folding structure of hundreds of wooden blocks, representing the transformation between surface and solid through a foldable one-dimensional chain. The sculpture grew out of an unexpected collaboration between a sculptor and two mathematicians, giving the structure a mathematical basis through which it is guaranteed to be foldable into essentially any three-dimensional shape.

[2,5-Bis(2,2′-bipyridyl-6-yl)-3,4-diazahexa-2,4-diene]dichloridomanganese(II): from a mononuclear compound to a three-dimensional supramolecular framework through C—H...Cl hydrogen bonds and π–π stacking interactions

2014 ◽  
Vol 70 (7) ◽  
pp. 718-721
Author(s):  
Zhengliang Lu ◽  
Yuanchao Zhao ◽  
Baolian Chen ◽  
Ximing Huang ◽  
Chunhua Fan
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Stacking Interactions ◽  
Dimensional Chain ◽  
Supramolecular Framework ◽  
One Dimensional ◽  
Pyramidal Geometry ◽  
Π Stacking ◽  
Square Pyramidal Geometry ◽  
Multifunctional Ligand

The title compound, [MnCl2(C24H20N6)], has been synthesized and characterized based on the multifunctional ligand 2,5-bis(2,2′-bipyridyl-6-yl)-3,4-diazahexa-2,4-diene (L). The MnIIcentre is five-coordinate with an approximately square-pyramidal geometry. TheLligand acts as a tridendate chelating ligand. The mononuclear molecules are bridged into a one-dimensional chain by two C—H...Cl hydrogen bonds. These chains are assembled into a two-dimensional layer through π–π stacking interactions between adjacent uncoordinated bipyridyl groups. Furthermore, a three-dimensional supramolecular framework is attained through π–π stacking interactions between adjacent coordinated bipyridyl groups.

Poly[hexabromobis[μ3-1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene]trimercury(II)]

2006 ◽  
Vol 62 (5) ◽  
pp. m1124-m1126 ◽  
Author(s):  
Xiao-Feng Wang ◽  
Yang Lv ◽  
Taka-aki Okamura ◽  
Wei-Yin Sun ◽  
Norikazu Ueyama
Keyword(s):  
Title Compound ◽  
Three Dimensional ◽  
Chain Structure ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Twofold Axis

In the title compound, [Hg3Br6(C21H24N6)2] n , the two Hg atoms (one of which lies on a twofold axis) are tetrahedrally coordinated by two Br atoms and two imidazole N atoms from two different 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene ligands. The complex has an infinite one-dimensional chain structure. The chains are further connected by C—H...Br interactions to form a three-dimensional framework.

A new one-dimensional CuIIcomplex with a three-dimensional supramolecular architecture incorporating benzene-1,3-dicarboxylate and 1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole

2017 ◽  
Vol 73 (2) ◽  
pp. 91-96 ◽  
Author(s):  
Jian-Hua Li ◽  
Meng-Di Zhu ◽  
Qiu-Ying Huang
Keyword(s):  
Thermogravimetric Analysis ◽  
Water Molecule ◽  
Main Chain ◽  
Three Dimensional ◽  
Donor Ligands ◽  
Dimensional Chain ◽  
Supramolecular Architecture ◽  
Coordination Environment ◽  
One Dimensional ◽  
Dimensional Network

Subtle modifications ofN-donor ligands can result in complexes with very different compositions and architectures. In the complexcatena-poly[[bis{1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole-κN3}copper(II)]-μ-benzene-1,3-dicarboxylato-κ3O1,O1′:O3], {[Cu(C8H4O4)(C10H9N5)2(H2O)]·2H2O}n, each CuIIion is six-coordinated by two N atoms from two crystallographically independent 1-[(1H-benzotriazol-1-yl)methyl]-1H-imidazole (bmi) ligands, by three O atoms from two symmetry-related benzene-1,3-dicarboxylate (bdic2−) ligands and by one water molecule, leading to a distorted CuN2O4octahedral coordination environment. The CuIIions are connected by bridging bdic2−anions to generate a one-dimensional chain. The bmi ligands coordinate to the CuIIions in monodentate modes and are pendant on opposite sides of the main chain. In the crystal, the chains are linked by O—H...O and O—H...N hydrogen bonds, as well as by π–π interactions, into a three-dimensional network. A thermogravimetric analysis was carried out and the fluorescence behaviour of the complex was also investigated.

scholarly journals Ethene-trans-1,2-bis(4-pyridinium) Dihydrogenphosphite and Dihydrogenphosphate Compounds Exhibiting Cooperative and Directed Hydrogen Bonds between Cations and Anions: H2bpe(H2PO3)2 and H2bpe(H2PO4)2 · H2O

2006 ◽  
Vol 61 (9) ◽  
pp. 1067-1071 ◽  
Author(s):  
Veysel T. Yilmaz ◽  
Selcuk Demir ◽  
William T. A. Harrison
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Dihydrogen Phosphate ◽  
Dimensional Chain ◽  
One Dimensional ◽  
Phosphate Ions

Abstract H2bpe(H2PO3)2 (1) and H2bpe(H2PO4)2 ・H2O (2) (H2bpe = ethene-trans-1,2-bis(4-pyridinium), H2PO3 = dihydrogenphosphite, and H2PO4 = dihydrogenphosphate) have been prepared and structurally characterized. In compound 1, the dihydrogenphosphite anions form dimers, with a P···P distance of 4.2073(7) Å , by two O-H···H hydrogen bonds, and the dimeric dihydrogenphosphite units interact with the H2bpe cations by way of N-H···O and O-H···O hydrogen bonds, resulting in a one-dimensional chain. The chains are held together by C-H···O interactions. In compound 2, the phosphate ions are connected by O-H···O hydrogen bonds into an unusual 2D square gridtype framework with P···P separations ranging from 4.7533(7) to 4.9506(8) Å . The H2bpe cations crosslink the dihydrogen phosphate layers by N-H···O hydrogen bonds, forming a three-dimensional supramolecular network with channels. The water molecules in compound 2 occupy these channels and make O-H···O bonds to adjacent phosphate O atoms and also O-H···O bonds to the next water O atom in the channel.

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