[2,5-Bis(2,2′-bipyridyl-6-yl)-3,4-diazahexa-2,4-diene]dichloridomanganese(II): from a mononuclear compound to a three-dimensional supramolecular framework through C—H...Cl hydrogen bonds and π–π stacking interactions
2014 ◽
Vol 70
(7)
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pp. 718-721
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The title compound, [MnCl2(C24H20N6)], has been synthesized and characterized based on the multifunctional ligand 2,5-bis(2,2′-bipyridyl-6-yl)-3,4-diazahexa-2,4-diene (L). The MnIIcentre is five-coordinate with an approximately square-pyramidal geometry. TheLligand acts as a tridendate chelating ligand. The mononuclear molecules are bridged into a one-dimensional chain by two C—H...Cl hydrogen bonds. These chains are assembled into a two-dimensional layer through π–π stacking interactions between adjacent uncoordinated bipyridyl groups. Furthermore, a three-dimensional supramolecular framework is attained through π–π stacking interactions between adjacent coordinated bipyridyl groups.
2014 ◽
Vol 70
(4)
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pp. 359-363
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2013 ◽
Vol 640
(7)
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pp. 1443-1448
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2006 ◽
Vol 62
(7)
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pp. o2797-o2799
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2016 ◽
Vol 72
(4)
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pp. 428-431
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2014 ◽
Vol 70
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pp. o1130-o1130
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2001 ◽
Vol 58
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pp. 94-108
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2006 ◽
Vol 62
(4)
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pp. 666-675
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2012 ◽
Vol 68
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pp. m209-m212
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Vol 70
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pp. o583-o583
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