Screening Technique for Lead and Cadmium in Toys and Other Materials Using Atomic Absorption Spectroscopy

2005 ◽  
Vol 82 (4) ◽  
pp. 611 ◽  
Author(s):  
Henry Brouwer
2003 ◽  
Vol 46 (4) ◽  
pp. 499-505 ◽  
Author(s):  
Marcilene Ferrari Barriquelo ◽  
Marinês Aparecida Juliatti ◽  
Margarete Soares da Silva ◽  
Ervim Lenzi

Lead (Pb) behavior was studied in soil treated twice with sewage sludge contaminated with lead at interval of 18 months. Soil samples received five different treatments: three with lead [0 (reference); 2,500; 5,000 mug g-1] and two with a mixture of lead and cadmium (interferer) (2,500 + 2,500 and 5,000 + 5,000 mug g-1, respectively). Vases containing treated soil were cultivated with maize in a greenhouse for 75 days. Pb was extracted using nitric perchloric digestion and analyzed by atomic absorption spectroscopy. The soil, containing sewage sludge contaminated by lead presented a higher concentration of Pb. The metal concentration remained constant in all treatments at 20-60 cm depth. No absorption of Pb by the plants was detected.


The estimation of selected heavy metals (Lead and Cd) was carried out using Atomic Absorption Spectroscopy (AAS). Therein, the levels of Lead (Pb) range from 1.0791+0.023ug/kg to 0.07060.+007ug/kg; the ranges of Cadmium (Cd) are 0.0552+0.003ug/kg to 0.0045+0.006ug/kg. The results revealed varying degrees of heavy metals in the selected plastics examined. Pb was highest in Plastic Bottles (PB) and lowest in Straw (S); whereas, Cd was highest in Straw and lowest in Plastic Bottles. KeyWords - Heavy metals, Pb, Cd, plastics, straw, plastic bottles


2018 ◽  
Vol 28 (4) ◽  
pp. 1259-1264
Author(s):  
Kiril Lisichkov ◽  
Katerina Atkovska ◽  
Neven Trajchevski ◽  
Orce Popovski ◽  
Nadica Todorovska

The presence of some chemical compounds at higher levels than maximum permissible concentrations (MPC) in the drinking water, suggests of water resources pollution. In this paper the following elements were analyzed: total arsenic, cadmium, lead, cooper and zinc. Twelve samples of water from the water supply system from the city of Skopje were examined during one year from three different springs. Also, ten samples of bottled water from three producers from the Macedonian market were tested.The determined average mass concentrations of total As, Cd(II), Pb(II), Cu(II) and Zn(II) in the analyzed water samples from the water supply system are 1.35 μg/l, 0.06 μg/l, 0.6 μg/l, 0.9 μg/l and 1,12 μg/l, respectively, and for the tested bottled water, the mean values ranges from 0.56 - 0.83 μg total As / l, 0.053 - 0.056 μg Cd(II)/l, 0.51 - 0.54 μg Pb(II)/l , 0.6 - 0.87 μg Cu(II)/l and 0.68 - 0.8 μg Zn(II)/l water.The following instrumental analytical methods and techniques were used for the analysis of the tested samples of drinking water: flame atomic absorption spectroscopy (AAS), atomic absorption spectroscopy with hydride cеll, electrothermal atomic absorption spectroscopy.The obtained results are shown in tables and graphic form. According to the obtained results a comparative analysis was carried out indicate that it is a water of good quality that can be used in different branches of the process industry.The obtained results in this paper do not exceed the values of the MPC of the Republic of Macedonia prescribed by the legal regulations for the drinking water, which confirm the health safety of the drinking water from the water supply system in the city of Skopje and the packed waters from the Macedonian market in relation to the tested elements.


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