Remoteness from Emission Sources Explains the Fractionation Pattern of Polychlorinated Biphenyls in the Northern Hemisphere

2010 ◽  
Vol 44 (16) ◽  
pp. 6183-6188 ◽  
Author(s):  
Harald von Waldow ◽  
Matthew MacLeod ◽  
Kevin Jones ◽  
Martin Scheringer ◽  
Konrad Hungerbühler



2013 ◽  
Vol 182 ◽  
pp. 283-290 ◽  
Author(s):  
Paromita Chakraborty ◽  
Gan Zhang ◽  
Sabine Eckhardt ◽  
Jun Li ◽  
Knut Breivik ◽  
...  


2016 ◽  
Vol 16 (17) ◽  
pp. 10911-10925 ◽  
Author(s):  
Yao Té ◽  
Pascal Jeseck ◽  
Bruno Franco ◽  
Emmanuel Mahieu ◽  
Nicholas Jones ◽  
...  

Abstract. This paper studies the seasonal variation of surface and column CO at three different sites (Paris, Jungfraujoch and Wollongong), with an emphasis on establishing a link between the CO vertical distribution and the nature of CO emission sources. We find the first evidence of a time lag between surface and free tropospheric CO seasonal variations in the Northern Hemisphere. The CO seasonal variability obtained from the total columns and free tropospheric partial columns shows a maximum around March–April and a minimum around September–October in the Northern Hemisphere (Paris and Jungfraujoch). In the Southern Hemisphere (Wollongong) this seasonal variability is shifted by about 6 months. Satellite observations by the IASI–MetOp (Infrared Atmospheric Sounding Interferometer) and MOPITT (Measurements Of Pollution In The Troposphere) instruments confirm this seasonality. Ground-based FTIR (Fourier transform infrared) measurements provide useful complementary information due to good sensitivity in the boundary layer. In situ surface measurements of CO volume mixing ratios at the Paris and Jungfraujoch sites reveal a time lag of the near-surface seasonal variability of about 2 months with respect to the total column variability at the same sites. The chemical transport model GEOS-Chem (Goddard Earth Observing System chemical transport model) is employed to interpret our observations. GEOS-Chem sensitivity runs identify the emission sources influencing the seasonal variation of CO. At both Paris and Jungfraujoch, the surface seasonality is mainly driven by anthropogenic emissions, while the total column seasonality is also controlled by air masses transported from distant sources. At Wollongong, where the CO seasonality is mainly affected by biomass burning, no time shift is observed between surface measurements and total column data.



Author(s):  
Hoang Quoc Anh ◽  
Shin Takahashi ◽  
Tu Binh Minh ◽  
Tran Manh Tri

Concentrations of polychlorinated biphenyls (PCBs) including 43 congeners of 10 homologs were determined in settled dust samples collected from urban houses and end-of-life vehicle (ELV) processing workshops in northern Vietnam. Concentrations of total 43 PCBs (ΣPCBs), 7 indicator PCBs (IN-PCBs), and 12 dioxin-like PCBs (DL-PCBs) in the ELV workshop dusts were significantly higher than those measured in the urban house dusts, suggesting ELV processing activities as potential sources of PCBs. However, concentrations of PCB-11 (3,3’-dichlorobiphenyl) in the urban house dusts (mean 4.5; range 1.2–8.7 ng/g) were markedly higher than levels found in the ELV workshop dusts (1.6; 0.46–5.4 ng/g). PCB-11 is a novel congener because it is only a trace component of technical PCB mixtures but identified as a major impurity of many organic pigments, especially diarylide yellow pigments. PCB patterns of the ELV workshop dusts were dominated by penta- and hexa-PCBs with major congeners as PCB-118, -138, -153, -110, and -101, which were also principal components of technical formulations such as Aroclor 1254, Kanechlor 500, and Sovol. Meanwhile, PCB-11 served as the most predominant congener detected in the urban house dusts, implying current emissions from paints and pigmented products; however, this point should be confirmed by further studies on the occurrence of PCBs in Vietnamese commercial products. Apart from PCB-11, the urban house dusts also contained elevated proportions of penta- and hexa-PCBs, suggesting residues from electrical equipment application in the past. Our results indicate that even though PCBs are legacy and banned chemicals, their presence has been observed in indoor environments due to their persistent nature and novel emission sources. Further studies on the occurrence and emission behavior of these pollutants should be conducted, including not only congeners in technical mixtures but also unintentionally produced compounds.



2005 ◽  
Vol 39 (35) ◽  
pp. 6502-6512 ◽  
Author(s):  
Hayley Hung ◽  
Sum Chi Lee ◽  
Frank Wania ◽  
Pierrette Blanchard ◽  
Ken Brice






1967 ◽  
Vol 31 ◽  
pp. 71-72
Author(s):  
B. F. Burke ◽  
P. P. Crowther ◽  
J. M. Moran ◽  
A. E. E. Rogers ◽  
J. A. Ball ◽  
...  

Interferometry gives effective diameters less than 20″ for the OH emission sources in W3and Sgr B2. The sources in W49and NGC 6334 contain two or more components, some of which are smaller than 25″.



2000 ◽  
Vol 179 ◽  
pp. 387-388
Author(s):  
Gaetano Belvedere ◽  
V. V. Pipin ◽  
G. Rüdiger

Extended AbstractRecent numerical simulations lead to the result that turbulence is much more magnetically driven than believed. In particular the role ofmagnetic buoyancyappears quite important for the generation ofα-effect and angular momentum transport (Brandenburg & Schmitt 1998). We present results obtained for a turbulence field driven by a (given) Lorentz force in a non-stratified but rotating convection zone. The main result confirms the numerical findings of Brandenburg & Schmitt that in the northern hemisphere theα-effect and the kinetic helicityℋkin= 〈u′ · rotu′〉 are positive (and negative in the northern hemisphere), this being just opposite to what occurs for the current helicityℋcurr= 〈j′ ·B′〉, which is negative in the northern hemisphere (and positive in the southern hemisphere). There has been an increasing number of papers presenting observations of current helicity at the solar surface, all showing that it isnegativein the northern hemisphere and positive in the southern hemisphere (see Rüdigeret al. 2000, also for a review).



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