The Determination of Complex Formation in Mixed Solvents by Gas Chromatography. The Tetrahydrofuran Complexes of Lithium Aluminum Hydride, Magnesium Bromide, and Several Grignard Reagents

1962 ◽  
Vol 1 (4) ◽  
pp. 921-925 ◽  
Author(s):  
Lloyd V. Guild ◽  
C. A. Hollingsworth ◽  
Darl H. McDaniel ◽  
Sunil Kumar Podder
Keyword(s):  
Gas Chromatography ◽  
Complex Formation ◽  
Lithium Aluminum Hydride ◽  
Mixed Solvents ◽  
Aluminum Hydride ◽  
Grignard Reagents ◽  
Lithium Aluminum ◽  
Magnesium Bromide

Diglyme as Solvent in the Gasometric Determination of Silanols by the Lithium Aluminum Hydride Method.

1963 ◽  
Vol 35 (9) ◽  
pp. 1308-1310 ◽  
Author(s):  
G. H. Barnes ◽  
N. E. Daughenbough
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Lithium Aluminum ◽  
Hydride Method

ChemInform Abstract: A Simple, Direct, and Reproducible Method for the Determination of Lithium Aluminum Hydride.

ChemInform ◽  
2010 ◽  
Vol 23 (20) ◽  
pp. no-no
Author(s):  
E. BROWN ◽  
A. LEZE ◽  
J. TOUET
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Lithium Aluminum ◽  
Reproducible Method

Synthesis oftrans- and cis-α-damascone

1978 ◽  
Vol 56 (10) ◽  
pp. 1368-1371 ◽  
Author(s):  
Hsing-Jang Liu ◽  
Hing-Kwok Hung ◽  
George L. Mhehe ◽  
M. L. Duarte Weinberg
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Complete Recovery ◽  
Lithium Aluminum ◽  
Magnesium Bromide ◽  
Keto Ester ◽  
Keto Esters ◽  
Hydride Reduction ◽  
Cis And Trans ◽  
Cis Isomer

Se lective thioketalization of a mixture of keto esters 5 and 6 resulted in the exclusive formation of thioketal 7 and complete recovery of keto ester 6. Lithium aluminum hydride reduction of thioketal 7 followed by Moffatt oxidation of the resulting alcohol 8 gave aldehyde 10 which on treatment with a mixture of cis- and trans-1-propenyl magnesium bromide afforded trans- alcohol 11 and its cis isomer 12. Manganese dioxide oxidation of alcohol 11 followed by desulfurization gave trans α-damascone (3). Similarly, alcohol 12 was converted to cis-α-damascone (4).

Determination of Lithium Aluminum Hydride in Solution

1948 ◽  
Vol 20 (4) ◽  
pp. 311-312 ◽  
Author(s):  
J. A. Krynitsky ◽  
J. E. Johnson ◽  
H. W. Carhart
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Lithium Aluminum

Lithium Aluminum Hydride as Reagent for Determination of Water

1950 ◽  
Vol 22 (2) ◽  
pp. 364-365 ◽  
Author(s):  
B. B. Baker ◽  
W. M. MacNevin
Keyword(s):  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Lithium Aluminum

Determination of the absolute stereochemistry of the fungal metabolite (R)-(−)-2-(4′-hydroxyphenyl)-2-hydroxyethanoic acid (pisolithin B)

1991 ◽  
Vol 69 (5) ◽  
pp. 772-778 ◽  
Author(s):  
Youla S. Tsantrizos ◽  
Kelvin K. Ogilvie
Keyword(s):  
Absolute Configuration ◽  
Lithium Aluminum Hydride ◽  
Optical Rotation ◽  
Aluminum Hydride ◽  
Lithium Aluminum ◽  
Fungal Metabolite ◽  
H Nmr ◽  
The Absolute ◽  
Absolute Stereochemistry

The antifungal antibiotic pisolithin B (p-hydroxymandelic acid, 2-(4′-hydroxyphenyl)-2-hydroxyethanoic acid, 1a) was shown to have the absolute (R) configuration. The stereochemistry was established via comparison of its optical rotation to that of its synthetic (R) and (S) enantiomers. The synthetic samples were prepared by the stereospecific reduction of the prochiral α-keto acid, p-hydroxybenzoylformic acid (2-(4′-hydroxyphenyl)-2-oxoethanoic acid, 2a), with (R) or (S)-2,2′-dihydroxy-1,1′-binaphthyl lithium aluminum hydride (BINAL-H). The absolute configuration and enantiomeric purity of both products were determined using the 1H NMR of their isobutyl esters in the presence of the chiral solvating agent (R)-(−)-2,2,2-trifluoro-1-(9-anthryl)ethanol. Key words: pisolithin B, p-hydroxymandelic acid, antifungal, absolute configuration.

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