Electronic effects in aromatic metal carbonyl complexes. II. Infrared and proton magnetic resonance spectra of substituted benzoic methyl ester tricarbonylchromium derivatives

1968 ◽  
Vol 7 (3) ◽  
pp. 579-584 ◽  
Author(s):  
Gilles Klopman ◽  
Klaus Noack
Keyword(s):  
Magnetic Resonance ◽  
Methyl Ester ◽  
Proton Magnetic Resonance ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Electronic Effects ◽  
Metal Carbonyl Complexes ◽  
Magnetic Resonance Spectra

Proton magnetic resonance spectra of leukotriene a methyl ester (I), leukotriene B methyl ester diacetate (II) and 12-epi-6-E,8-Z-leukotriene B methyl ester diacetate (III; 5-S,12-di-HETE)

Tetrahedron ◽  
1982 ◽  
Vol 38 (17) ◽  
pp. 2653-2657 ◽  
Author(s):  
E.J. Corey ◽  
Paul B. Hopkins ◽  
Alan E. Barton ◽  
Ben Bangerter ◽  
Pierre Borgeat
Keyword(s):  
Magnetic Resonance ◽  
Methyl Ester ◽  
Proton Magnetic Resonance ◽  
Magnetic Resonance Spectra

Electronic effects in group VIB arene-metal carbonyl complexes and related species

1965 ◽  
Vol 4 (4) ◽  
pp. 324-331 ◽  
Author(s):  
J.D. Holmes ◽  
D.A.K. Jones ◽  
R. Pettit
Keyword(s):  
Related Species ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Electronic Effects ◽  
Metal Carbonyl Complexes

ChemInform Abstract: MULTINUCLEAR MAGNETIC RESONANCE STUDIES OF GROUP 6 METAL CARBONYL COMPLEXES OF UNSYMMETRICAL BISPHORPHORUS LIGANDS

1981 ◽  
Vol 12 (45) ◽  
Author(s):  
I. J. COLQUHOUN ◽  
S. O. GRIM ◽  
W. MCFARLANE ◽  
J. D. MITCHELL ◽  
P. H. SMITH
Keyword(s):  
Magnetic Resonance ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Magnetic Resonance Studies ◽  
Metal Carbonyl Complexes ◽  
Group 6 ◽  
Multinuclear Magnetic Resonance

scholarly journals Computational Characterization of Bidentate P-Donor Ligands: Direct Comparison to Tolman’s Electronic Parameters

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3176 ◽  
Author(s):  
Tímea Kégl ◽  
Noémi Pálinkás ◽  
László Kollár ◽  
Tamás Kégl
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Metal Carbonyl ◽  
Donor Ligands ◽  
Carbonyl Complexes ◽  
Electronic Effects ◽  
Functional Theory ◽  
Metal Carbonyl Complexes ◽  
Electronic Parameters

The applicability of two types of transition-metal carbonyl complexes as appropriate candidates for computationally derived Tolman’s ligand electronic parameters were examined with density functional theory (DFT) calculations employing the B97D3 functional. Both Pd(0)L2(CO) and HRh(I)L2(CO) complexes correlated well with the experimental Tolman Electronic Parameter scale. For direct comparison of the electronic effects of diphosphines with those of monophosphines, the palladium-containing system is recommended. The t r a n s influence of various phosphines did not show a major difference, but the decrease of the H-Rh-P angle from linear can cause a significant change.

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