Reactions of metal-metal multiple bonds. 7. Addition of the halogens chlorine, bromine and iodine and diisopropyl peroxide to hexaisopropoxydimolybdenum (M.tplbond.M). Dinuclear oxidative-addition reactions accompanied by metal-metal bond-order changes from 3 to 2 to 1

1981 ◽  
Vol 20 (3) ◽  
pp. 871-876 ◽  
Author(s):  
Malcolm H. Chisholm ◽  
Charles C. Kirkpatrick ◽  
John C. Huffman
Keyword(s):  
Bond Order ◽  
Oxidative Addition ◽  
Addition Reactions ◽  
Multiple Bonds ◽  
Metal Bond ◽  
Metal Metal

Reductive elimination of [AlH2]+ from a cationic Ga-Al dihydride

2021 ◽  
Author(s):  
Jun Okuda ◽  
Louis J. Morris ◽  
Laurent Maron ◽  
Ambre Carpentier
Keyword(s):  
Oxidative Addition ◽  
Reductive Elimination ◽  
Metal Bond ◽  
Metal Metal

Oxidative addition of TMEDA-supported [AlH2]+ to [{BDI}Ga] (BDI = {HC(C(CH3)N(2,6-iPr2-C6H3))2) provides [{BDI}Ga(H)-Al(H)(tmeda)]¬[B(C6H3-3,5-Me2)4] (TMEDA = N,N,N’N’-tetramethylethylene¬diamine) with a covalent metal-metal bond. The reaction is readily reversed by substituting TMEDA for an...

A Highly Reduced V23+Unit with a Metal−Metal Bond Order of 3.5

2003 ◽  
Vol 125 (8) ◽  
pp. 2026-2027 ◽  
Author(s):  
F. Albert Cotton ◽  
Elizabeth A. Hillard ◽  
Carlos A. Murillo
Keyword(s):  
Bond Order ◽  
Metal Bond ◽  
Metal Metal

Systematic Variation of Metal–Metal Bond Order in Metal–Chromium Complexes

2013 ◽  
Vol 135 (35) ◽  
pp. 13142-13148 ◽  
Author(s):  
Laura J. Clouston ◽  
Randall B. Siedschlag ◽  
P. Alex Rudd ◽  
Nora Planas ◽  
Shuxian Hu ◽  
...  
Keyword(s):  
Bond Order ◽  
Systematic Variation ◽  
Chromium Complexes ◽  
Metal Bond ◽  
Metal Metal

Prediction of high bond-order metal–metal multiple-bonds in heterobimetallic 3d–4f/5f complexes [TM–M{N(o-[NCH2P(CH3)2]C6H4)3}] (TM = Cr, Mn, Fe; M = U, Np, Pu, and Nd)

2019 ◽  
Vol 48 (34) ◽  
pp. 12867-12879 ◽  
Author(s):  
Shu-Xian Hu ◽  
Erli Lu ◽  
Stephen T. Liddle
Keyword(s):  
Quantum Chemical ◽  
Bond Order ◽  
Relativistic Quantum ◽  
Quantum Chemical Study ◽  
Chemical Study ◽  
Multiple Bonds ◽  
Metal Metal ◽  
High Bond ◽  
Metal Metal Bonds ◽  
Metal Bonds

A relativistic quantum chemical study on hypothetical but potentially experimentally realisable TM–actinide and –neodymium complexes reveals the similarity in their structures but the differences in the multiplicity of the metal–metal bonds.

Transition-metal derivatives of the cyclopentadienylphosphine bridging unit. VI. Oxidation, oxidative addition, insertion, and metal-metal bond formation in dirhodium complexes

1991 ◽  
Vol 10 (7) ◽  
pp. 2443-2456 ◽  
Author(s):  
Xiaodong. He ◽  
Andre. Maisonnat ◽  
Francoise. Dahan ◽  
Rene. Poilblanc
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Oxidative Addition ◽  
Metal Bond ◽  
Metal Metal ◽  
Metal Derivatives ◽  
Dirhodium Complexes ◽  
Derivatives Of

Oxidative addition of a phosphorus-oxygen-phosphorus linkage and metal-metal bond formation across a dimolybdenum cage

1992 ◽  
Vol 11 (4) ◽  
pp. 1579-1586 ◽  
Author(s):  
Haiying Yang ◽  
Edward H. Wong ◽  
Jerry P. Jasinski ◽  
Roman Y. Pozdniakov ◽  
Richard Woudenberg
Keyword(s):  
Bond Formation ◽  
Oxidative Addition ◽  
Metal Bond ◽  
Metal Metal

Dinuclear oxidative addition reactions using an isostructural series of Ni2, Co2, and Fe2 complexes

2017 ◽  
Vol 46 (17) ◽  
pp. 5493-5497 ◽  
Author(s):  
Michael J. Behlen ◽  
You-Yun Zhou ◽  
Talia J. Steiman ◽  
Sudipta Pal ◽  
Douglas R. Hartline ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Addition Reactions ◽  
Oxidative Additions ◽  
Redox Active ◽  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

Dinuclear oxidative additions at metal–metal bonds are facilitated by redox-active supporting ligands.

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