Iso-Selective Ring-Opening Polymerization of rac-Lactide Catalyzed by Crown Ether Complexes of Sodium and Potassium Naphthalenolates

2015 ◽  
Vol 54 (4) ◽  
pp. 1737-1743 ◽  
Author(s):  
Jiao Xiong ◽  
Jinjin Zhang ◽  
Yangyang Sun ◽  
Zhongran Dai ◽  
Xiaobo Pan ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (39) ◽  
pp. 24055-24063 ◽  
Author(s):  
Bing-Bing Wu ◽  
Lu-Lu Tian ◽  
Zhong-Xia Wang

Crown ether complexes of sodium and potassium iminophenoxides were demonstrated to catalyze the stereoselective polymerization of rac-lactide.


RSC Advances ◽  
2017 ◽  
Vol 7 (19) ◽  
pp. 11657-11664 ◽  
Author(s):  
Bing-Bing Wu ◽  
Zhong-Xia Wang

Crown ether complexes of potassium quinolin-8-olates were synthesized and demonstrated to catalyze the stereoselective polymerization of rac-lactide.


1981 ◽  
Vol 14 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Toshiyuki Uryu ◽  
Kissho Kitano ◽  
Katsuhiro Ito ◽  
Junichi Yamanouchi ◽  
Kei Matsuzaki

2015 ◽  
Vol 137 (45) ◽  
pp. 14439-14445 ◽  
Author(s):  
Stefan Naumann ◽  
Philip B. V. Scholten ◽  
James A. Wilson ◽  
Andrew P. Dove

2017 ◽  
Vol 46 (18) ◽  
pp. 5938-5945 ◽  
Author(s):  
Mathew Anker ◽  
Choumini Balasanthiran ◽  
Vagulejan Balasanthiran ◽  
Malcolm H. Chisholm ◽  
Savithra Jayaraj ◽  
...  

Al(iii) acts as a Lewis acid for the ring-opening of an epoxide by Cl− attack and this yields stereo selective ring-opening polymerization of rac-lactide to yield iso-polylactide.


2017 ◽  
Vol 129 (42) ◽  
pp. 13167-13170 ◽  
Author(s):  
Na Zhao ◽  
Chuanli Ren ◽  
Huaike Li ◽  
Yunxin Li ◽  
Shaofeng Liu ◽  
...  

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