Rare Examples of Transition-Metal−Main-Group Metal Heterometallic Metal−Organic Frameworks from Gallium and Indium Dipyrrinato Complexes and Silver Salts:  Synthesis and Framework Variability

2007 ◽  
Vol 46 (26) ◽  
pp. 11213-11223 ◽  
Author(s):  
Jay R. Stork ◽  
Van S. Thoi ◽  
Seth M. Cohen
Keyword(s):  
Transition Metal ◽  
Metal Organic Frameworks ◽  
Main Group ◽  
Silver Salts ◽  
Group Metal ◽  
Main Group Metal ◽  
Metal Organic

On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

2010 ◽  
Vol 39 (44) ◽  
pp. 10588 ◽  
Author(s):  
Clara J. Durango-García ◽  
J. Oscar C. Jiménez-Halla ◽  
Marcela López-Cardoso ◽  
Virginia Montiel-Palma ◽  
Miguel A. Muñoz-Hernández ◽  
...  
Keyword(s):  
Transition Metal ◽  
Theoretical Calculations ◽  
Main Group ◽  
Metal Bond ◽  
Group Metal ◽  
Main Group Metal

Novel isomorphism of two hexagonal non-centrosymmetric hybrid crystals of M(en)3Ag2I4 (M = transition metal Mn2+ or main-group metal Mg2+; en = ethylenediamine)

CrystEngComm ◽  
2018 ◽  
Vol 20 (3) ◽  
pp. 356-361 ◽  
Author(s):  
Xin Chen ◽  
Zhi-Yuan Yao ◽  
Chen Xue ◽  
Zhu-Xi Yang ◽  
Jian-Lan Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal ◽  
Hybrid Crystals ◽  
First Time

For the first time, a main-group metal complex is used as a template for the formation of hybrid crystal structures and isomorphic hybrid crystals are obtained using transition and main-group metal complexes.

Studies on main group metal—transition metal bonded compounds

1977 ◽  
Vol 129 (1) ◽  
pp. 1-16 ◽  
Author(s):  
John N.St Denis ◽  
William Butler ◽  
Milton D. Glick ◽  
John P. Oliver
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Group Metal ◽  
Main Group Metal
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