AbstractDuring the last decades, the merger of photocatalysis with transition metal chemistry has been surfaced as a sustainable tool in modern molecular syntheses. This Account highlights major advances in synergistic photo-enabled C‒H activations. Inspired by our homogenous ruthenium- and copper-catalyzed C‒H activations in the absence of an exogenous photosensitizer, this Account describes the recent progress on heterogeneous photo-induced C‒H activation enabled by immobilized hybrid catalysts until September 2021, with a topical focus on recyclability as well as robustness of the heterogeneous photocatalyst.
Transition Metal Chemistry is an international journal which deals with all aspects of the preparation of transition metal-based molecular compounds as well as including their physical, structural, kinetic, catalytic and biological properties, and their use in chemical synthesis as well as their application in the widest context, their role in naturally occurring systems and more.
We predicted the stable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the...
Transition metal chemistry is a challenging playground for quantum chemical methods owing to the simultaneous presence of static and dynamic electron correlation effects in many systems. Wavefunction based multireference (MR)...
C–H activation by immobilized heterogeneous photocatalysts
