Novel Operating Method for Controlling Latex Particle Size Distribution in Emulsion Polymerization of Vinyl Acetate

2001 ◽  
Vol 40 (23) ◽  
pp. 5177-5183 ◽  
Author(s):  
Naoto Ohmura ◽  
Keigo Kitamoto ◽  
Takeshi Yano ◽  
Kunio Kataoka
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Emulsion Polymerization ◽  
Vinyl Acetate ◽  
Latex Particle ◽  
Operating Method

Outstanding Practical Problems in Emulsion Polymerization with Particular Reference to Dienic Hydrocarbons

1970 ◽  
Vol 43 (6) ◽  
pp. 1451-1464 ◽  
Author(s):  
E. W. Duck
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Emulsion Polymerization ◽  
Latex Particle ◽  
Film Forming ◽  
Solids Content ◽  
Styrene Butadiene

Abstract The incentives and problems associated with 100% conversions of polymerization are discussed with reference to the heterogeneity produced by emulsion polymerization of styrene-butadiene rubbery copolymers. Stereospecific problems are also considered together with the influence of latex particle size and particle size distribution on viscosity and solids content and film-forming properties.

Semibatch Seeded Emulsion Polymerization of Acrylic Monomers: Bimodal Particle Size Distribution

1997 ◽  
Vol 34 (7) ◽  
pp. 1221-1236 ◽  
Author(s):  
Chorng-Shyan Chern ◽  
Tseng-Jung Chen ◽  
Shinn-Yih Wu ◽  
Horng-Bin Chu ◽  
Chun-Fu Huang
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Emulsion Polymerization ◽  
Seeded Emulsion Polymerization ◽  
Acrylic Monomers

Effects of Emulsifier Concentration on Nucleation Mode of Emulsion Polymerization of Styrene

2013 ◽  
Vol 395-396 ◽  
pp. 399-402 ◽  
Author(s):  
Li Bao Mei ◽  
Xiao Qin Xiao ◽  
Yong Li ◽  
Yan Lin Sun
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Emulsion Polymerization ◽  
Homogeneous Nucleation ◽  
Particle Number ◽  
Nucleation Mode ◽  
P Fraction ◽  
Emulsifier Concentration

The nucleation mode of emulsion polymerization of styrene under different emulsifier (SDS) concentrations is studied in this paper. Some factors such as conversion, particle number (Np), fraction of coverage, polydispersion index (PDI) and particle size distribution (PSD) of the reactions were investigated. The results show that when [SD is less than its CMC, homogeneous nucleation dominates. But when [SD is more than its CMC, micelle nucleation plays the major role.

Evolution of multimodal particle size distribution in vinyl acetate/butyl acrylate emulsion copolymerizations

2003 ◽  
Vol 41 (14) ◽  
pp. 2232-2249 ◽  
Author(s):  
Charles D. Immanuel ◽  
Timothy J. Crowley ◽  
Edward S. Meadows ◽  
Cajetan F. Cordeiro ◽  
Francis J. Doyle
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Vinyl Acetate ◽  
Butyl Acrylate ◽  
Acrylate Emulsion
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