scholarly journals Continuous Heterogeneously Catalyzed Oxidation of Benzyl Alcohol Using a Tube-in-Tube Membrane Microreactor

2015 ◽  
Vol 54 (16) ◽  
pp. 4183-4189 ◽  
Author(s):  
Gaowei Wu ◽  
Achilleas Constantinou ◽  
Enhong Cao ◽  
Simon Kuhn ◽  
Moataz Morad ◽  
...  
2019 ◽  
Vol 4 (1) ◽  
pp. 302-310
Author(s):  
Nelson C. Coronel ◽  
Márcio J. da Silva ◽  
Sukarno O. Ferreira ◽  
Rene C. da Silva ◽  
Ricardo Natalino

2015 ◽  
Vol 19 (12) ◽  
pp. 1973-1979 ◽  
Author(s):  
Achilleas Constantinou ◽  
Gaowei Wu ◽  
Albert Corredera ◽  
Peter Ellis ◽  
Donald Bethell ◽  
...  

2015 ◽  
Vol 723 ◽  
pp. 601-604 ◽  
Author(s):  
Ran Li ◽  
Ge Wang ◽  
Yan Chun Liu ◽  
Xiao Bin Chen ◽  
Zhi Min Sun ◽  
...  

Benzyl alcohol was selectively oxidized to benzaldehyde with iron (III) complexed to tetra amido macrocyclic ligands (FeIII–TAML) as catalyst and 30% H2O2 as oxidant. The effect of reaction temperature, reaction time, solvent, amount of catalyst and oxidant on the reaction of catalyzed oxidation of benzyl alcohol were explored. The conversion and selectivity of this oxidation reaction were calculated from calibrated GC yields of benzyl alcohol and benzaldehyde. When oxidation reaction was conducted under the conditions: solvent NMMO: ethanol = 1: 1, n (H2O2): n (benzyl alcohol) = 2, n (catalyst): n (benzyl alcohol) = 1%, temperature 80 ̊C and reaction time 60 minutes, the conversion was 91.23% and the selectivity was 90.12%.


ChemCatChem ◽  
2010 ◽  
Vol 2 (7) ◽  
pp. 827-833 ◽  
Author(s):  
Sander A. Tromp ◽  
Inga Matijošytė ◽  
Roger A. Sheldon ◽  
Isabel W. C. E. Arends ◽  
Guido Mul ◽  
...  

Micromachines ◽  
2021 ◽  
Vol 12 (11) ◽  
pp. 1307
Author(s):  
Mamoru Hyodo ◽  
Hitomi Iwano ◽  
Takayoshi Kasakado ◽  
Takahide Fukuyama ◽  
Ilhyong Ryu

High-power UV-LED irradiation (365 nm) effectively accelerated the decatungstate-anion-catalyzed oxidation of benzyl alcohol 1 to benzoic acid 3 via benzaldehyde 2. As the power of the UV-LED light increased, both the selectivity and yield of benzoic acid also increased. The reaction was finished within 1 h to give 3 in a 93% yield using 2 mol% of decatungstate anion catalyst. The combination of a flow photoreactor and high-power irradiation accelerated the oxidation reaction to an interval of only a few minutes.


2009 ◽  
Vol 2 (1) ◽  
pp. 7-11 ◽  
Author(s):  
Praveen K. Tandon ◽  
Priy B. Dwivedi ◽  
Manisha Purwar ◽  
Satpal Singh

2002 ◽  
Vol 34 (7) ◽  
pp. 421-429 ◽  
Author(s):  
A. E. Mucientes ◽  
F. Santiago ◽  
M. C. Almena ◽  
F. J. Poblete ◽  
A. M. Rodriguez-Cervantes

2011 ◽  
Vol 31 (11) ◽  
pp. 1369-1373
Author(s):  
Cheng LIU ◽  
Rong TAN ◽  
Donghong YIN ◽  
Ningya YU ◽  
Yuxu ZHOU

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