A Microwave Study and Centrifugal Distortion Analysis of the Pyrrole-CO Complex

1994 ◽  
Vol 98 (17) ◽  
pp. 4551-4563 ◽  
Author(s):  
Ryan P. A. Bettens ◽  
Sonja R. Huber ◽  
A. Bauder
Keyword(s):  
Centrifugal Distortion ◽  
Distortion Analysis

scholarly journals Millimeter Wave Spectrum and Centrifugal Distortion Analysis of Difluorochloromethane CHF2Cl in the Ground State

1990 ◽  
Vol 45 (9-10) ◽  
pp. 1165-1168 ◽  
Author(s):  
R. Spiehl ◽  
A. Guarnieri
Keyword(s):  
Millimeter Wave ◽  
Ground State ◽  
Wave Spectrum ◽  
Sixth Order ◽  
Centrifugal Distortion ◽  
Rotational Spectra ◽  
Vibrational Ground State ◽  
Distortion Analysis

Abstract The rotational spectra of CHF235Cl and CHF237Cl (CFC22) in the vibrational ground state between 42 and 214 GHz are reported. A centrifugal distortion analysis up to the sixth order is carried out.

Determination of a High Potential Barrier Hindering Internal Rotation from the Ground State Spectrum. The Methylbarrier of Ethylbromide

1985 ◽  
Vol 40 (6) ◽  
pp. 575-587 ◽  
Author(s):  
J. Gripp ◽  
H. Dreizler ◽  
R. Schwarz
Keyword(s):  
Hyperfine Structure ◽  
Internal Rotation ◽  
Potential Barrier ◽  
Ground State ◽  
Rotational Spectrum ◽  
Centrifugal Distortion ◽  
Vibrational Ground State ◽  
Distortion Analysis ◽  
High Potential Barrier

For ethylbromide a determination of the parameters of internal rotation is given derived from the rotational spectrum of the torsional and vibrational ground state. The Br-hyperfine structure is reanalysed with higher precision. As high J transitions were measured a centrifugal distortion analysis was necessary.

Centrifugal Distortion Analysis and Study of T 2 -Relaxation for l-Type Doublet Transitions of Nitrous Oxide ( 15N2O) by a Microwave Pulse Technique

1993 ◽  
Vol 48 (5-6) ◽  
pp. 720-724
Author(s):  
H. W. Nicolaisen ◽  
H. Mäder
Keyword(s):  
Microwave Pulse ◽  
Binary Collision ◽  
Line Center ◽  
Centrifugal Distortion ◽  
Pressure Broadening ◽  
Bending Vibration ◽  
Pulse Technique ◽  
Distortion Analysis ◽  
First Excited State ◽  
Centrifugal Distortion Constants

We investigated l-type doublet transitions of 15N20 in the first excited state of the degenerate bending vibration v2 with 14 < J < 34. From analysis of the J-dependence of the line center frequencies, the doubling constant q(0) was obtained together with the first and second order centrifugal distortion constants q(1) and q(2) respectively. For the lines in the J-band (4 to 8.2 GHz) and K-band (18 to 26.5 GHz) we have also investigated the pressure broadening due to self-collisions with use of the transient emission technique. The experimental results for the pressure broadening parameter Γp are compared with predictions from binary collision theory, based on the modified Murphy-Boggs perturbative treatment.

The microwave spectrum of cyanogen iodide: Hyperfine structure by coupling of two nuclei and centrifugal distortion analysis

1988 ◽  
Vol 129 (2) ◽  
pp. 381-387 ◽  
Author(s):  
J. Gripp ◽  
H. Dreizler ◽  
J. Gadhi ◽  
G. Wlodarczak ◽  
J. Legrand ◽  
...  
Keyword(s):  
Hyperfine Structure ◽  
Microwave Spectrum ◽  
Centrifugal Distortion ◽  
Distortion Analysis ◽  
Cyanogen Iodide

The rotational spectrum of acetone: Internal rotation and centrifugal distortion analysis

1986 ◽  
Vol 118 (2) ◽  
pp. 355-362 ◽  
Author(s):  
J.M. Vacherand ◽  
B.P. Van Eijck ◽  
J. Burie ◽  
J. Demaison
Keyword(s):  
Internal Rotation ◽  
Rotational Spectrum ◽  
Centrifugal Distortion ◽  
Distortion Analysis

Centrifugal Distortion Analysis of a Near-Spherical Top, SO2F2: The First Determination of All Six Quartic Centrifugal Distortion Constants for an Asymmetric Top

2000 ◽  
Vol 200 (1) ◽  
pp. 55-64 ◽  
Author(s):  
Kamil Sarka ◽  
Jean Demaison ◽  
Laurent Margulès ◽  
Ilona Merke ◽  
Nils Heineking ◽  
...  
Keyword(s):  
Centrifugal Distortion ◽  
Distortion Analysis ◽  
Asymmetric Top ◽  
Centrifugal Distortion Constants

Centrifugal distortion analysis of the rotational spectrum of cyclopropenylidene

1986 ◽  
Vol 125 (4) ◽  
pp. 383-388 ◽  
Author(s):  
M. Bogey ◽  
C. Demuynck ◽  
J.L. Destombes
Keyword(s):  
Rotational Spectrum ◽  
Centrifugal Distortion ◽  
Distortion Analysis
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