A kinetic investigation of the reactions sodium + ozone and sodium monoxide + ozone over the temperature range 207-377 K

1993 ◽  
Vol 97 (17) ◽  
pp. 4459-4467 ◽  
Author(s):  
J. M. C. Plane ◽  
C. F. Nien ◽  
M. R. Allen ◽  
M. Helmer
Keyword(s):  
Kinetic Investigation ◽  
Temperature Range ◽  
Sodium Monoxide

Thermoreactivity of Sol-Gel Precursor for ZnO-Based Thin Films

2006 ◽  
Vol 514-516 ◽  
pp. 73-77 ◽  
Author(s):  
Viorica Muşat ◽  
Paula M. Vilarinho ◽  
Regina da Conceição Corredeira Monteiro ◽  
Elvira Fortunato ◽  
E. Segal
Keyword(s):  
Differential Equation ◽  
Thin Films ◽  
Activation Energy ◽  
Thermal Decomposition ◽  
Organic Compounds ◽  
Sol Gel ◽  
Hexagonal Lattice ◽  
Kinetic Investigation ◽  
Temperature Range ◽  
Carbonate Hydroxide

The thermoreactivity of a zinc acetate non-alkoxide solution used for the preparation of ZnO-based thin films was investigated in the temperature range 20-600°C by TG-DTA, XRD and SEM data. We found that the formation in air of ZnO crystallites from the sol-gel precursor occurs above 150°C simultaneously with the decomposition of an intermediary compound, most probably carbonate hydroxide (sclarite and/or hydrozincite). At 200 °C, the crystalline structure is well defined in terms of ZnO hexagonal lattice parameters, although residual organic compounds and water were not yet fully removed and an amorphous phase coexists. A kinetic investigation on the thermal decomposition of sol-gel precursor from DTA data using Kissinger differential equation is also presented. Apparent activation energy values of about. 100 kJ mol-1 corresponding to the nonisothermal decomposition of solid precursors in the temperature range 170-250oC have been found.

Kinetic investigation of the reactions of NCO radicals with alkanes in the temperature range 294 to 1113 K

1994 ◽  
Vol 99 (3-4) ◽  
pp. 491-498 ◽  
Author(s):  
Alexander Schuck ◽  
Hans-Robert Volpp ◽  
Jürgen Wolfrum
Keyword(s):  
Kinetic Investigation ◽  
Temperature Range

A kinetic investigation of the reaction Ca + O3over the temperature range 213–383 K

1993 ◽  
Vol 89 (5) ◽  
pp. 763-769 ◽  
Author(s):  
Magdalena Helmer ◽  
John M. C. Plane ◽  
Matthew R. Allen
Keyword(s):  
Kinetic Investigation ◽  
Temperature Range
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