Gas-phase reactions of the vinoxy radical with oxygen and nitric oxide

1983 ◽  
Vol 87 (20) ◽  
pp. 3902-3905 ◽  
Author(s):  
D. Gutman ◽  
H. H. Nelson
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Gas Phase Reactions

Gas-phase reactions of nitric oxide with atomic lanthanide cations: Room-temperature kinetics and periodicity in reactivity

2006 ◽  
Vol 249-250 ◽  
pp. 385-391 ◽  
Author(s):  
Voislav Blagojevic ◽  
Eric Flaim ◽  
Michael J.Y. Jarvis ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Room Temperature ◽  
Gas Phase Reactions ◽  
Lanthanide Cations

scholarly journals The HNO− radical anion: A proposed intermediate in diazeniumdiolate synthesis using nitric oxide and alkoxides

2018 ◽  
Vol 25 (1) ◽  
pp. 82-85 ◽  
Author(s):  
Zhe-Chen Wang ◽  
Ya-Ke Li ◽  
Sheng-Gui He ◽  
Veronica M Bierbaum
Keyword(s):  
Nitric Oxide ◽  
Reaction Mechanism ◽  
Gas Phase ◽  
Radical Anion ◽  
Room Temperature ◽  
Hydrogen Transfer ◽  
Gas Phase Reactions ◽  
Ionic Product

The strategy of synthesizing diazeniumdiolates (X–N(O)=NO−) through the coexistence of nitric oxide and alkoxides (RO−) was introduced by Wilhelm Traube 120 years ago. Today, despite the wide use of diazeniumdiolate derivatives to release nitric oxide in the treatment of cancer, the first step of the reaction mechanism for diazeniumdiolate synthesis remains a mystery and is thought to be complex. We have studied the gas-phase reactions of nitric oxide with alkoxides at room temperature. An electron-coupled hydrogen transfer is observed, and the radical anion HNO− is the only ionic product in these reactions. HNO− can further react with nitric oxide to form N2O and HO−.

Gas-phase reactions of ethyl radicals with nitric oxide

1964 ◽  
Vol 60 ◽  
pp. 371 ◽  
Author(s):  
G. L. Pratt ◽  
J. H. Purnell
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Gas Phase Reactions ◽  
Ethyl Radicals

Gas Phase Reactions of Fluorine Atoms

1973 ◽  
Vol 51 (12) ◽  
pp. 2041-2046 ◽  
Author(s):  
Thomas Long Pollock ◽  
William Ernest Jones
Keyword(s):  
Nitric Oxide ◽  
Gas Phase ◽  
Flow System ◽  
Fluid Mixing ◽  
Gas Phase Reactions ◽  
Rate Of Reaction ◽  
Chemiluminescent Reaction

The rate of reaction of F atoms with a series of compounds, CH4, CH3F, CH2F2, CHF3, CHClF2, HCl, CBrF3, NH3, and PH3 has been determined relative to the chemiluminescent reaction[Formula: see text]by photometry. The fluorine atoms were produced in a flow system from the fluid mixing of molecular fluorine and nitric oxide diluted with argon.

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