ESR spin-label study of poly(methyl methacrylate) chain segment rotational dynamics in dilute solution

1986 ◽  
Vol 90 (22) ◽  
pp. 6038-6044 ◽  
Author(s):  
J. Pilar ◽  
J. Labsky
Keyword(s):  
Methyl Methacrylate ◽  
Spin Label ◽  
Rotational Dynamics ◽  
Dilute Solution ◽  
Chain Segment ◽  
Label Study ◽  
Poly Methyl Methacrylate

scholarly journals Spin Label Study of the Factors Affecting Molecular Motion of Poly(methyl methacrylate)

1996 ◽  
Vol 28 (8) ◽  
pp. 690-695 ◽  
Author(s):  
Shigetaka Shimada ◽  
Keiichi Kashima
Keyword(s):  
Methyl Methacrylate ◽  
Spin Label ◽  
Molecular Motion ◽  
Label Study ◽  
Factors Affecting ◽  
Poly Methyl Methacrylate

Spin-label study of immiscible polymers: 4. Location of chain ends in blends of poly(methyl methacrylate) and poly(2-ethylhexyl methacrylate)

Polymer ◽  
1994 ◽  
Vol 35 (16) ◽  
pp. 3384-3388 ◽  
Author(s):  
G.G. Cameron ◽  
D. Stewart ◽  
R. Buscall ◽  
J. Nemcek
Keyword(s):  
Methyl Methacrylate ◽  
Spin Label ◽  
Label Study ◽  
Poly Methyl Methacrylate ◽  
Immiscible Polymers

Spin label study of the free-volume relaxation in a poly(ethylene oxide)/poly(methyl methacrylate) blend

1992 ◽  
Vol 25 (10) ◽  
pp. 2771-2773 ◽  
Author(s):  
Shigetaka Shimada ◽  
Yasuro Hori ◽  
Hisatsugu Kashiwabara
Keyword(s):  
Ethylene Oxide ◽  
Methyl Methacrylate ◽  
Free Volume ◽  
Spin Label ◽  
Volume Relaxation ◽  
Label Study ◽  
Poly Methyl Methacrylate ◽  
Poly Ethylene Oxide ◽  
Poly Ethylene

Spin-label study of immiscible polymers: 5. Blends of labelled poly(2-ethyl hexyl methacrylate) with poly(methyl methacrylate) and polystyrene

Polymer ◽  
1995 ◽  
Vol 36 (16) ◽  
pp. 3071-3074 ◽  
Author(s):  
G.G. Cameron ◽  
M.Y. Qureshi ◽  
D. Stewart ◽  
R. Buscall ◽  
J. Nemcek
Keyword(s):  
Methyl Methacrylate ◽  
Spin Label ◽  
Label Study ◽  
Poly Methyl Methacrylate ◽  
Immiscible Polymers ◽  
Ethyl Hexyl ◽  
Hexyl Methacrylate

PROTON MAGNETIC RESONANCE LINE WIDTH AS A FUNCTION OF POLYMER TACTICITY

1966 ◽  
Vol 44 (2) ◽  
pp. 153-156 ◽  
Author(s):  
S. Brownstein ◽  
D. M. Wiles
Keyword(s):  
Magnetic Resonance ◽  
Methyl Methacrylate ◽  
Proton Magnetic Resonance ◽  
Chloroform Solution ◽  
Spin Coupling ◽  
Solution Viscosity ◽  
Dilute Solution ◽  
Poly Methyl Methacrylate ◽  
Resonance Line Width ◽  
Polymer Tacticity

The high resolution proton magnetic resonance spectra of five samples of poly(methyl methacrylate) in chloroform solution have been measured with 100 Mc/s equipment. The widths of the absorption lines arising from the protons of the α-methyl and the methoxyl groups have been compared. The widths are greater when the polymer is predominantly syndiotactic than when it is predominantly isotactic. It is concluded that isotactic samples have the more extended conformation in chloroform solution. An analogy with dilute solution viscosity measurements is outlined in support of this conclusion. Differences between the widths of the lines of the methylene protons in a completely isotactic poly(methyl methacrylate) sample are attributed to long range spin coupling.

Scattering Function of Syndiotactic Poly(methyl methacrylate) in Dilute Solution

1994 ◽  
Vol 27 (15) ◽  
pp. 4259-4262 ◽  
Author(s):  
Takenao Yoshizaki ◽  
Hisao Hayashi ◽  
Hiromi Yamakawa
Keyword(s):  
Methyl Methacrylate ◽  
Dilute Solution ◽  
Scattering Function ◽  
Poly Methyl Methacrylate
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