Dielectric permittivity effects on electron-capture reactions by charged and polar scavengers: tert-butyl alcohol/water mixed solvents

1988 ◽  
Vol 92 (18) ◽  
pp. 5142-5147 ◽  
Author(s):  
P. Chandani Senanayake ◽  
Gordon R. Freeman



1976 ◽  
Vol 54 (23) ◽  
pp. 3800-3808 ◽  
Author(s):  
Nicole Desrosiers ◽  
Jacques E. Desnoyers

The enthalpies, heat capacities, and volumes of transfer of the tetrabutylammonium ion from water to urea–water, tert-butyl alcohol–water, and sodium chloride–water mixtures have been calculated at 25 °C using the scaled-particle theory. In general, the signs, magnitudes, and overall trends in the cosolvent concentration dependence of the properties are predicted from the cavity contributions only. These calculations are found to be very sensitive to the diameters chosen for the various species.For these calculations it was necessary to measure with a dilatometer the coefficients of thermal expansion of tert-butyl alcohol–water mixtures as a function of concentration and temperature.





1957 ◽  
Vol 78 (8) ◽  
pp. 1155-1158
Author(s):  
Ei Koizumi ◽  
Hiroshi Miyamoto ◽  
Shouzou Watanabe


1954 ◽  
Vol 46 (6) ◽  
pp. 59-59
Author(s):  
J Westwater ◽  
L Audrieth




2004 ◽  
Vol 120 (10) ◽  
pp. 4759-4767 ◽  
Author(s):  
Vania Calandrini ◽  
Antonio Deriu ◽  
Giuseppe Onori ◽  
Ruep E. Lechner ◽  
Jörg Pieper


1991 ◽  
Vol 87 (10) ◽  
pp. 1569-1573 ◽  
Author(s):  
Ashok C. Kumbharkhane ◽  
Sanjay M. Puranik ◽  
Suresh C. Mehrotra


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