Micellar effects on the reactivity of the hydrated electron with benzene

1970 ◽  
Vol 74 (26) ◽  
pp. 4608-4609 ◽  
Author(s):  
Larry K. Patterson ◽  
Janos H. Fendler
Keyword(s):  
Hydrated Electron ◽  
Micellar Effects

Radiolysis studies on the corrosion inhibitors 1 -hexyn-3-ol, cinnamonitrile, and 1,3-diethyl-2-thiourea

1995 ◽  
Vol 73 (12) ◽  
pp. 2137-2142 ◽  
Author(s):  
A.J. Elliot ◽  
M.P. Chenier ◽  
D.C. Ouellette
Keyword(s):  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Temperature Dependence ◽  
Rate Constant ◽  
Rate Constants ◽  
Corrosion Inhibitors ◽  
Hydrated Electron

In this publication we report: (i) the rate constants for reaction of the hydrated electron with 1-hexyn-3-ol ((8.6 ± 0.3) × 108 dm3 mol−1 s−1 at 18 °C), cinnamonitrile ((2.3 ± 0.2) × 1010 dm3 mol−1 s−1 at 20 °C), and 1,3-diethyl-2-thiourea ((3.5 ± 0.3) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile and diethylthiourea, the temperature dependence up to 200 °C and 150 °C, respectively, is also reported; (ii) the rate constants for the reaction of the hydroxyl radical with 1-hexyn-3-ol ((5.5 ± 0.5) × 109 dm3 mol−1 s−1 at 20 °C), cinnamonitrile ((9.2 ± 0.3) × 109 dm3 mol−1 s−1 at 21 °C), and diethylthiourea ((8.0 ± 0.8) × 108 dm3 mol−1 s−1 at 22 °C). For cinnamonitrile, the temperature dependence up to 200 °C is also reported; (iii) the rate constant for the hydrogen atom reacting with 1-hexyn-3-ol ((4.3 ± 0.4) × 109 dm3 mol−1 s−1 at 20 °C). Keywords: radiolysis, corrosion inhibitors, rate constants.

A Unified Electron Transfer Model for the Different Precursors and Excited States of the Hydrated Electron

2001 ◽  
Vol 105 (37) ◽  
pp. 8434-8439 ◽  
Author(s):  
Tak W. Kee ◽  
Dong Hee Son ◽  
Patanjali Kambhampati ◽  
Paul F. Barbara
Keyword(s):  
Electron Transfer ◽  
Excited States ◽  
Hydrated Electron ◽  
Transfer Model

Laser-induced formation of pyrenyloxy radical from 1-hydoxypyrene and further oxidation: Micellar effects

2006 ◽  
Vol 182 (2) ◽  
pp. 168-173 ◽  
Author(s):  
Yoshihiro Mori ◽  
Hiroyuki Shinoda ◽  
Taku Nakano ◽  
Ryozo Takasu ◽  
Taiji Kitagawa
Keyword(s):  
Micellar Effects

Solvent and micellar effects upon the reaction of NADH models with methylene blue

1986 ◽  
Vol 105 (11) ◽  
pp. 494-502 ◽  
Author(s):  
J. F. J. Engbersen ◽  
A. Koudijs ◽  
H. C. van der Plas
Keyword(s):  
Methylene Blue ◽  
Micellar Effects

scholarly journals Micellar Effects on Base-Catalyzed Isomerization of Prostaglandin A1and Prostaglandin A2

1978 ◽  
Vol 51 (4) ◽  
pp. 1229-1230 ◽  
Author(s):  
Kaneto Uekama ◽  
Fumitoshi Hirayama ◽  
Shyukou Yamasaki
Keyword(s):  
Micellar Effects ◽  
Prostaglandin A2

Kinetics and efficiency of the hydrated electron-induced dehalogenation by the sulfite/UV process

2014 ◽  
Vol 62 ◽  
pp. 220-228 ◽  
Author(s):  
Xuchun Li ◽  
Jingyun Fang ◽  
Guifang Liu ◽  
Shujuan Zhang ◽  
Bingcai Pan ◽  
...  
Keyword(s):  
Hydrated Electron
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