Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO)3(PR3)2H2 where R = isopropyl and cyclopentyl

G. Rattan K. Khalsa; Gregory J. Kubas; Clifford J. Unkefer; Lori Stepan Van der Sluys; Kimberly A. Kubat-Martin

doi:10.1021/ja00166a020

Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO)3(PR3)2H2 where R = isopropyl and cyclopentyl

Journal of the American Chemical Society ◽

10.1021/ja00166a020 ◽

1990 ◽

Vol 112 (10) ◽

pp. 3855-3860 ◽

Cited By ~ 27

Author(s):

G. Rattan K. Khalsa ◽

Gregory J. Kubas ◽

Clifford J. Unkefer ◽

Lori Stepan Van der Sluys ◽

Kimberly A. Kubat-Martin

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Kinetics And Thermodynamics

ChemInform Abstract: Molecular Hydrogen Complexes of the Transition Metals. Part 7. Kinetics and Thermodynamics of the Interconversion Between Dihydride and Dihydrogen Forms of W(CO)3(PR3)2H2 Where R: Isopropyl and Cyclopentyl.

ChemInform ◽

10.1002/chin.199033239 ◽

1990 ◽

Vol 21 (33) ◽

Author(s):

G. R. K. KHALSA ◽

G. J. KUBAS ◽

C. J. UNKEFER ◽

L. S. VAN DER SLUYS ◽

K. A. KUBAT-MARTIN

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Kinetics And Thermodynamics

ChemInform Abstract: Molecular Hydrogen Complexes of the Transition Metals. Part 2. Evidence for a New Complex, Mo(CO)(dppe)2(H2), and for Solution Equilibrium Between Dihydrogen and Dihydride Forms, M - η2-H2↔ H - M - H, in W(CO)3(PR3)2(H2).

Chemischer Informationsdienst ◽

10.1002/chin.198629245 ◽

1986 ◽

Vol 17 (29) ◽

Author(s):

G. J. KUBAS ◽

R. R. RYAN ◽

D. A. WROBLESKI

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Solution Equilibrium

ChemInform Abstract: Molecular Hydrogen Coordination to Transition Metals

ChemInform ◽

10.1002/chin.198847344 ◽

1988 ◽

Vol 19 (47) ◽

Author(s):

G. J. KUBAS

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

Scrutinizing the substituent effect on Mo-based electrocatalysts for molecular hydrogen release through axial–equatorial decomposition: a DFT study

Physical Chemistry Chemical Physics ◽

10.1039/c9cp00670b ◽

2019 ◽

Vol 21 (30) ◽

pp. 16601-16614 ◽

Cited By ~ 3

Author(s):

Diana Yepes ◽

Pablo Jaque ◽

Jorge I. Martínez-Araya

Keyword(s):

Substituent Effect ◽

Molecular Hydrogen ◽

Aqueous Media ◽

Hydrogen Release ◽

Dft Study ◽

Kinetics And Thermodynamics

The effect of electron-donating and -withdrawing groups is studied in terms of axial and equatorial locations at the p-pyridine rings in the [(PY5Me2)MoO]2+ for the H2 release in aqueous media. It opens a way to modify its kinetics and thermodynamics.

Reduction of carbon dioxide by molecular hydrogen in the presence of complexes of the transition metals

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00855315 ◽

1972 ◽

Vol 21 (10) ◽

pp. 2263-2264 ◽

Cited By ~ 2

Author(s):

I. S. Kolornnikov ◽

T. S. Lobeeva ◽

M. E. Vol'pin

Keyword(s):

Carbon Dioxide ◽

Transition Metals ◽

Molecular Hydrogen

Reactivity of Transition Metals (Pd, Pt, Cu, Ag, Au) toward Molecular Hydrogen Dissociation: Extended Surfaces versus Particles Supported on TiC(001) or Small Is Not Always Better and Large Is Not Always Bad

The Journal of Physical Chemistry C ◽

10.1021/jp2024445 ◽

2011 ◽

Vol 115 (23) ◽

pp. 11666-11672 ◽

Cited By ~ 62

Author(s):

Tatiana Gomez ◽

Elizabeth Florez ◽

José A. Rodriguez ◽

Francesc Illas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Hydrogen Dissociation ◽

Extended Surfaces

Molecular Hydrogen Coordination to Transition Metals

Comments on Inorganic Chemistry ◽

10.1080/02603598808072297 ◽

1988 ◽

Vol 7 (1) ◽

pp. 17-40 ◽

Cited By ~ 32

Author(s):

Gregory J. Kubas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

Accounts of Chemical Research ◽

10.1021/ar00147a005 ◽

1988 ◽

Vol 21 (3) ◽

pp. 120-128 ◽

Cited By ~ 450

Author(s):

Gregory J. Kubas

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Sigma Bond

Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction

Journal of the American Chemical Society ◽

10.1021/ja00269a027 ◽

1986 ◽

Vol 108 (9) ◽

pp. 2294-2301 ◽

Cited By ~ 70

Author(s):

Harvey J. Wasserman ◽

Gregory J. Kubas ◽

Robert R. Ryan

Keyword(s):

Transition Metals ◽

Molecular Hydrogen

Molecular hydrogen diffusion overpotential and local cell hydrogen transfer processes at electrodes of palladium, palladium alloys and other transition metals, and implications for theories of hydrogen overpotential

Surface Technology ◽

10.1016/0376-4583(80)90013-8 ◽

1980 ◽

Vol 11 (1) ◽

pp. 1-16 ◽

Cited By ~ 15

Author(s):

F.A. Lewis

Keyword(s):

Transition Metals ◽

Molecular Hydrogen ◽

Hydrogen Transfer ◽

Hydrogen Diffusion ◽

Palladium Alloys ◽

Transfer Processes ◽

Local Cell ◽

Hydrogen Overpotential