A stepwise mechanism for gas-phase unimolecular ion decompositions. Isotope effects in the fragmentation of tert-butoxide anion

1987 ◽  
Vol 109 (4) ◽  
pp. 961-970 ◽  
Author(s):  
William Tumas ◽  
Robert F. Foster ◽  
Mark J. Pellerite ◽  
John I. Brauman
Keyword(s):  
Gas Phase ◽  
Isotope Effects ◽  
Stepwise Mechanism

scholarly journals Isotope Effects Suggest a Stepwise Mechanism for Berberine Bridge Enzyme

Biochemistry ◽  
2012 ◽  
Vol 51 (37) ◽  
pp. 7342-7347 ◽  
Author(s):  
Helena M. Gaweska ◽  
Kenneth M. Roberts ◽  
Paul F. Fitzpatrick
Keyword(s):  
Isotope Effects ◽  
Stepwise Mechanism ◽  
Berberine Bridge Enzyme

Full-dimensional analytical potential energy surface describing the gas-phase Cl + C2H6 reaction and kinetics study of rate constants and kinetic isotope effects

2018 ◽  
Vol 20 (6) ◽  
pp. 3925-3938 ◽  
Author(s):  
Cipriano Rangel ◽  
Joaquin Espinosa-Garcia
Keyword(s):  
Potential Energy ◽  
Potential Energy Surface ◽  
Gas Phase ◽  
Energy Surface ◽  
Isotope Effects ◽  
Hydrogen Abstraction ◽  
System P ◽  
Abstraction Reaction ◽  
Analytical Potential ◽  
Oppenheimer Approximation

Within the Born–Oppenheimer approximation a full-dimensional analytical potential energy surface, PES-2017, was developed for the gas-phase hydrogen abstraction reaction between the chlorine atom and ethane, which is a nine body system.

Sign in / Sign up

Export Citation Format

Share Document