Cobalt carbonyl catalyzed reactions of esters and lactones with hydrosilane and carbon monoxide. A novel synthetic method for the introduction of the siloxymethylidene group

1986 ◽  
Vol 108 (23) ◽  
pp. 7361-7373 ◽  
Author(s):  
Naoto. Chatani ◽  
Satoru. Fujii ◽  
Yasuhiro. Yamasaki ◽  
Shinji. Murai ◽  
Noboru. Sonoda
Keyword(s):  
Carbon Monoxide ◽  
Synthetic Method ◽  
Cobalt Carbonyl ◽  
Catalyzed Reactions

Cobalt carbonyl-catalyzed reactions of cyclic ethers with a hydrosilane and carbon monoxide. A new synthetic reaction equivalent to nucleophilic oxymethylation

1989 ◽  
Vol 111 (20) ◽  
pp. 7938-7946 ◽  
Author(s):  
Toshiaki Murai ◽  
Eiji Yasui ◽  
Shinzi Kato ◽  
Yoshio Hatayama ◽  
Satoshi Suzuki ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Cyclic Ethers ◽  
Cobalt Carbonyl ◽  
Synthetic Reaction ◽  
Catalyzed Reactions

Cobalt carbonyl catalyzed reaction of tetrahydrofurans with a hydrosilane and carbon monoxide. A new reaction pathway leading to enol silyl ethers.

1985 ◽  
Vol 26 (22) ◽  
pp. 2683-2684 ◽  
Author(s):  
Toshiaki Murai ◽  
Shinzi Kato ◽  
Shinji Murai ◽  
Yoshio Hatayama ◽  
Noboru Sonoda
Keyword(s):  
Carbon Monoxide ◽  
Reaction Pathway ◽  
Cobalt Carbonyl ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

Cobalt carbonyl catalyzed reaction of tetrahydrofurans with a hydrosilane and carbon monoxide at atmospheric pressure

1983 ◽  
Vol 2 (12) ◽  
pp. 1883-1885 ◽  
Author(s):  
Toshiaki Murai ◽  
Yoshio Hatayama ◽  
Shinji Murai ◽  
Noboru Sonoda
Keyword(s):  
Carbon Monoxide ◽  
Atmospheric Pressure ◽  
Cobalt Carbonyl

The Stereochemistry of Organometallic Compounds. LX. Rhodium-Catalyzed Reactions of Hydrogen and Carbon Monoxide With Alkenylanilines

1994 ◽  
Vol 47 (6) ◽  
pp. 1043 ◽  
Author(s):  
D Anastasiou ◽  
EM Campi ◽  
H Chaouk ◽  
GD Fallon ◽  
WR Jackson ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Carbon Monoxide ◽  
Single Crystal ◽  
Structure Determination ◽  
Cross Coupling ◽  
Organometallic Compounds ◽  
Single Crystal Structure ◽  
Crystal Structure Determination ◽  
X Ray ◽  
Catalyzed Reactions

Rhodium- catalysed reactions of o- or p- cyano-N-allylanilines with H2/CO give N- arylpyrrolidine aldehydes resulting from a double hydroformylation sequence. In contrast reactions of o- or p-methyl-N-allylanilines or N- allylaniline itself with H2/CO give ' dimeric ' compounds resulting from self-condensation reactions of an initially formed hydroformylation product together with varying amounts of the double hydroformylation product. Similar reactions of o-cyano-N-but-3-enylanilines give low yields of double hydroformylation products and major products arising from hydrogenation or cross coupling of intermediate enamines. The structure of one of these products, N-2-cyanophenyl-5-(N′-2-cyanophenyl-3-methyl-pyrrolidin-2-yl)-1,2,3,4-tetrahydropyridine (17) (IUPAC name: 2-[5-{1-(2-cyanophenyl)-3-methylpyrrolidin-2-yl}-1,2,3,4-tetrahydropyridin-1-yl] benzonitrile ) was confirmed by an X-ray single-crystal structure determination.

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