Preparation and properties of molybdenum and tungsten dinitrogen complexes. 18. Preparation and characterization of novel .mu.3-dinitrogen mixed metal complexes

1983 ◽  
Vol 105 (6) ◽  
pp. 1680-1682 ◽  
Author(s):  
Tamotsu Takahashi ◽  
Teruyuki Kodama ◽  
Atsushi Watakabe ◽  
Yasuzo Uchida ◽  
Masanobu Hidai



1978 ◽  
Vol 40 (9) ◽  
pp. 1686-1687 ◽  
Author(s):  
M. Nagao ◽  
H. Inoue ◽  
S. Yanagisawa


2007 ◽  
pp. 2949 ◽  
Author(s):  
Azizolla Beheshti ◽  
William Clegg ◽  
Sophie H. Dale ◽  
Reza Hyvadi ◽  
Farzanh Hussaini


2008 ◽  
pp. 5059 ◽  
Author(s):  
Snežana Rajković ◽  
Csilla Kállay ◽  
Richárd Serényi ◽  
Gerasimos Malandrinos ◽  
Nick Hadjiliadis ◽  
...  


2020 ◽  
Vol 34 (2) ◽  
pp. 313-321
Author(s):  
H. İlkimen ◽  
R. S. Canlıdinç

Four novel hetero dimetallic mixed metal complexes of 2,6-pyridinedicarboxylic acid       (H2dipic), [Ni(H2O)5Co(dipic)2] (1), [Co(H2O)5Co(dipic)2][Ni(H2O)5Ni(dipic)2][Co(dipic)(H2O)3] (2), [Cu(H2O)5Ni(dipic)2]2[Co(dipic)(H2O)] (3) and [Ni(H2O)5Cu(dipic)2]2[Co(dipic)(H2O)] (4) have been prepared and characterized by elemental, AAS, spectral (IR and UV-Vis), and thermal analyses, as well as by using magnetic measurement and molar conductivity techniques. The results indicate that metal ions coordinate with 2,6-pyridinedicarboxylate ions (dipic2-) nitrogen atoms and carboxylate oxygen atoms of ligands. The mole ratio of dipic2- and metal ions in the complexes have been determined to be 2:2 (Co, Ni) for 1, 5:5 (3Co, 2Ni) for 2, 5:5 (Co, 2Ni and 2Cu) for 3 and 5:5 (Co, 2Ni and 2Cu) for 4 according to the results of elemental analysis. The structures of 1-4 might be proposed as octahedral ([Cu(dipic)(H2O)] unit for 2 square plane) according to results of spectroscopic analysis. The TG and DTA properties of compounds have been studied.                     KEY WORDS: 2,6-Pyridinedicarboxylic acid, Mixed metal, Metal complex   Bull. Chem. Soc. Ethiop. 2020, 34(2), 313-321 DOI: https://dx.doi.org/10.4314/bcse.v34i2.9



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