New probes for electron-transfer processes. Evidence supporting the single-electron-transfer mechanism in additions of carbanions to dienones

1983 ◽  
Vol 105 (9) ◽  
pp. 2922-2923 ◽  
Author(s):  
Dennis Liotta ◽  
Manohar Saindane ◽  
Liladhar Waykole
Keyword(s):  
Electron Transfer ◽  
Transfer Mechanism ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Electron Transfer Mechanism ◽  
Transfer Processes ◽  
Electron Transfer Processes

scholarly journals Synthesis of indanes via carbene-catalyzed single-electron-transfer processes and cascade reactions

2017 ◽  
Vol 53 (87) ◽  
pp. 11952-11955 ◽  
Author(s):  
Yuhuang Wang ◽  
Xingxing Wu ◽  
Yonggui Robin Chi
Keyword(s):  
Electron Transfer ◽  
Michael Addition ◽  
Cascade Reactions ◽  
Cascade Reaction ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Transfer Processes ◽  
Electron Transfer Processes

An NHC-catalyzed cascade reaction involving an SET process and two sequential Michael addition steps for the synthesis of indanes is disclosed.

Cyclic voltammetry of diphenylpicrylhydrazyl in tetrahydrofuran

1968 ◽  
Vol 46 (8) ◽  
pp. 1337-1340 ◽  
Author(s):  
B. Lionel Funt ◽  
Derek G. Gray
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Free Radical ◽  
Anionic Polymerization ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Transfer Processes ◽  
Suitable Medium ◽  
The Stability ◽  
Electron Transfer Processes

Cyclic voltammetry has revealed four reversible single electron transfer processes in the oxidation and reduction of diphenylpicrylhydrazyl (DPPH) in tetrahydrofuran (THF). These are associated with a cation, a free radical, a monoanion, a dianion radical, and a trianion of DPPH.THF is a good solvent for cyclic voltammetry as evidenced by the stability of the products generated at the electrodes. It is also one of the few excellent solvents for anionic polymerization and is therefore a remarkably suitable medium for studies of electropolymerization phenomena.

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