Oxidative addition of alkyl halides to zero-valent palladium complexes. Mechanisms

1976 ◽  
Vol 98 (19) ◽  
pp. 5841-5849 ◽  
Author(s):  
J. K. Stille ◽  
K. S. Y. Lau
Keyword(s):  
Oxidative Addition ◽  
Palladium Complexes ◽  
Alkyl Halides

ChemInform Abstract: OXIDATIVE ADDITION OF ALKYL HALIDES TO ZERO-VALENT PALLADIUM COMPLEXES. MECHANISMS

1976 ◽  
Vol 7 (50) ◽  
pp. no-no
Author(s):  
J. K. STILLE ◽  
K. S. Y. LAU
Keyword(s):  
Oxidative Addition ◽  
Palladium Complexes ◽  
Alkyl Halides

Oxidative addition of n-alkyl halides to diimine–dialkylplatinum(ii) complexes: a closer look at the kinetic behaviors

2008 ◽  
pp. 2414 ◽  
Author(s):  
S. Masoud Nabavizadeh ◽  
S. Jafar Hoseini ◽  
Badri Z. Momeni ◽  
Nahid Shahabadi ◽  
Mehdi Rashidi ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides

Reactions of the Ni(0) Compound Ni(PPh3)4 with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates

2018 ◽  
Vol 37 (15) ◽  
pp. 2450-2467 ◽  
Author(s):  
Ryley Kehoe ◽  
Markshun Mahadevan ◽  
Adeela Manzoor ◽  
Gillian McMurray ◽  
Patrick Wienefeld ◽  
...  
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides ◽  
Addition Reactions ◽  
Radical Processes

A Mechanistic Investigation of the Oxidative Addition of Alkyl Halides to Palladium Atoms

1977 ◽  
Vol 137 (1) ◽  
pp. 113-130 ◽  
Author(s):  
Kenneth J. Klabunde ◽  
John S. Roberts
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides ◽  
Mechanistic Investigation

scholarly journals Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates

Molecules ◽  
2019 ◽  
Vol 24 (8) ◽  
pp. 1458 ◽  
Author(s):  
Kimihiro Komeyama ◽  
Ryusuke Tsunemitsu ◽  
Takuya Michiyuki ◽  
Hiroto Yoshida ◽  
Itaru Osaka
Keyword(s):  
Electron Transfer ◽  
Oxidative Addition ◽  
Alkyl Halides ◽  
Cobalt Catalysts ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Mild Conditions

A direct reductive homo-coupling of alkyl tosylates has been developed by employing a combination of nickel and nucleophilic cobalt catalysts. A single-electron-transfer-type oxidative addition is a pivotal process in the well-established nickel-catalyzed coupling of alkyl halides. However, the method cannot be applied to the homo-coupling of ubiquitous alkyl tosylates due to the high-lying σ*(C–O) orbital of the tosylates. This paper describes a Ni/Co-catalyzed protocol for the activation of alkyl tosylates on the construction of alkyl dimers under mild conditions.

scholarly journals Neutral, cationic and anionic organonickel and -palladium complexes supported by iminophosphine/phosphinoenaminato ligands

2020 ◽  
Vol 49 (2) ◽  
pp. 322-335 ◽  
Author(s):  
Tomás G. Santiago ◽  
Carmen Urbaneja ◽  
Eleuterio Álvarez ◽  
Elena Ávila ◽  
Pilar Palma ◽  
...  
Keyword(s):  
Ligand Exchange ◽  
Oxidative Addition ◽  
Palladium Complexes ◽  
Addition Reactions ◽  
Acid Base

Ligand exchange and oxidative addition reactions allow the synthesis of Ni(ii) and Pd(ii) complexes with deprotonable iminophosphine ligands. The acid–base behavior of iminophosphine ligands coordinated to organometallic Ni(ii) fragments is analyzed.

ChemInform Abstract: OXIDATIVE ADDITION IN THE COUPLING OF ALKYLGOLD(I) WITH ALKYL HALIDES

1974 ◽  
Vol 5 (18) ◽  
pp. no-no
Author(s):  
A. TAMAKI ◽  
J. K. KOCHI
Keyword(s):  
Oxidative Addition ◽  
Alkyl Halides
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